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WP5 Status Report Months 31 to 50
Křišťál, Jiří ; Stavárek, Petr ; Jiřičný, Vladimír
Within WP5 in this reporting period focused on the development of a new intensified reactor concept for sulph(on)ation reaction. Based on the previous hydrodynamic experiments and mathematical models we designed a new reactor – microSulphonator. We also constructed and manufactured several prototypes that were later tested with model fluids. Experimental data were used for the validation of the models defined previously. Results of this period served as a basis for the final microSulphonators to be tested in the PGB pilot plant during the demonstration phase of the F3 project.
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Oxidation of Volatile Organic Compounds in a Multifunctional High Temperature and High-Pressure Cassette Microreactor
Vajglová, Zuzana ; Stavárek, Petr ; Křišťál, Jiří ; Jirátová, Květa ; Ludvíková, Jana ; Jiřičný, Vladimír
Analysis of the total oxidation of ethanol including reaction intermediates data obtained in the examined reactors on the temperature showed that differentmaterial applied in the construction of reactors and their arrangement give slightly different results of catalyst testing, the ones obtained from microreactor being more precise. More precise control of reaction temperature due to higher heat transfer capabilities and limited backmixing of reaction mixture in a packed bed microreactor is advantageous and leads to the more accurate results of oxidation catalysts testing. However, it is necessary to ensure in order the material used for the reactor construction did not affect the catalytic reaction. The results accomplished confirm that microreactors are not only suitable for performing of catalytic reactions in a laboratory scale but also promising way for creation of new, safer and cleaner production processes.
Plný tet: SKMBT_C22014050212452 -  PDF
Plný text: content.csg - PDF
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Performance of Continuous Micro Photo Reactor – Comparison with Batch Process
Drhová, Magdalena ; Hejda, S. ; Křišťál, Jiří ; Klusoň, Petr
Utilization of the flow chemistry as well as microreactors belongs to the latest trends in chemical engineering. Continuous microreactors of various kinds can be found in the literature, for example the micromixers, micro packed beds, or micro photo reactors. In order to evaluate the benefits of microtechnology application for the given process, the performance of a particular microreactor needs to be compared with the conventional setup. This contribution presents the performance of a continuous micro photo reactor in comparison with a batch process. Two model reactions were selected: the catalyzed photooxidation of 4-chlorophenol (4-CP) and the singlet oxygen chemical quencher 9,10-dimethylanthracene (DMA) in dimethylformamide. The tests were carried out using advanced opto-chemical apparatus with a well-defined light filter corresponding to the absorption bands of the used photo catalysts.
Plný tet: SKMBT_C22012102414080 - PDF
Plný text: content.csg - PDF
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