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Mechanical properties of fiber reinforced composites for automotive applications
Bayer, Adam ; Žídek, Jan (referee) ; Jančář, Josef (advisor)
Bachelor’s thesis deals with studying mechanical features of fiber composites. As a matrix was chosen PMMA and as reinforcement was chosen glass fabric. Theoretical part sums up contemporary issues of polymer composites in automotive industry such as their production techniques and methods of impregnation. In experimental part were prepared samples by block polymerization of 30 % solution PMMA in monomer with initiator by 65° Celsius warmth oath, when was fabric directly unfolded in pre-polymer solution. On these samples were executed tensile tests by testing device Zwick and these samples were compared with results of theoreticaly calculated values.
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Stress-strain analysis of skull implant
Hřičiště, Michal ; Borák, Libor (referee) ; Marcián, Petr (advisor)
Lebeční implantáty se používají jako náhrady částí lebečních kosti, které v důsledku zranění nebo nemoci ztratili svou funkci. Důležitým faktorem, který ovlivňuje funkci celé soustavy implantátu, jsou jeho mechanické projevy. Tato práce stručně shrnuje současné znalosti v oblasti rekonstrukce lebečních defektů a popisuje srovnání různých tvarů stěn implantátu vytvořených z různých materiálů, na základě deformační napěťové analýzy modelu neurocrania s umístěným implantátem, zatíženým nitrolebečním tlakem a vnějším zatížením.
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Automotive plastics with increased scratch resistance
Vida, Mikuláš ; Kučera, František (referee) ; Jančář, Josef (advisor)
The aim of this bachelor thesis was the investigation of changes of mechanical and rheological properties of nanocomposites based on PMMA, where filler was fumed silica of four types (different surface area and producer). The thesis focuses on the theoretical part of the current state of research, preparation and properties of nanocomposites. The solvent method was chosen for the preparation of nanocomposites, where silica was mixed with dissolved PMMA. Tensile mechanical properties were measured below Tg, while viscoelastic response was measured above Tg. Silica had not significant influence on the modulus below Tg, but above Tg (180 °C) both modulus, storage and loss, have increased with increasing silica content and with increasing frequency (0,1–100 Hz). The particle size and surface area of silica in a content of 1 % influenced storage modulus of nanocomposites more with respect to the content of 2 %. For samples containing 1 % showed that the significant role played particle size and surface area of silica. The greatest increase of storage and loss modulus of PMMA was reached for silica M-5 in content 1 %. All type of silica decreased tensile strength and strain with increasing silica content in the same way.
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Polymer nanocomposites with PMMA matrix
Kostková, Jana ; Žídek, Jan (referee) ; Jančář, Josef (advisor)
This bachelor thesis deals with s study of mechanical and viscoelastic properties of nanocomposites with PMMA matrix filled with different types of surface-modified silica, which differed by the specific surface area, surface treatment and particle size. Nanocomposites were prepared by dissolving, where nanofillers were injected into the dissolved matrix. Nanocomposite samples were tested in tensil and viscoelastic properties were determined till the softening point by dynamic-mechanical analysis (DMA). All types of nanofillers had almost no effect on tensile modulus of nanocomposites at room temperature (it was not reduced) one type of silica at a content 2 %, which was also confirmed by the DMA. The temperature DMA measurements showed that samples containing 2 % of silica were generally thermally more stable compared with nanocomposites containing 1 % of silica. Storage modulus of nanocomposites, except two ones, were similar or lower such pure PMMA to temperature 66 C, then the trend reversed. Loss modulus of all samples was one order of magnitude lower then the elastic modulus.
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Plasmonic Structures In PMMA Resist
Urbánek, Michal ; Krátký, Stanislav ; Šimík, M. ; Kolařík, Vladimír ; Horáček, Miroslav ; Matějka, Milan
Some metal material can exhibit special physical phenomenon which is called plasmon resonance. This effect can be used in optical applications where designed structures, using this effect, have special function as optical filters, polarizers, holograms etc. This papers deals with preparation of plasmonic structures in poly(methyl methacrylate) (PMMA) resist which is the most common material used for e-beam processing. Designed structures were prepared by e-beam writer with Gaussian beam and accelerating voltage of 100 kV. These structures are usually prepared into negative tone resist hydrogen silsesquioxane (HSQ). We prepared these structures by unusual way into positive resist PMMA due to unavailability and cost of HSQ resist. By this way we are able to achieve high resolution of structures suitable for special optical application. Exposed structures were developed in isopropyl based developer. Final structures after development were coated by two metal layers (first one is Ag layer, second one is gold) by magnetron sputtering and vacuum evaporation. The quality of prepared plasmonic structures was examined by confocal laser scanning microscopy (CLSM) and scanning electron microscopy (SEM).
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Gel Polymer Electrolytes
Vondrák, Jiří ; Sedlaříková, M. ; Nováček, T. ; Reiter, J.
The research and development of lithium and lithium ion batteries, the necessity of a new kind of electrolytes appeared. These electrolytes have to be strictly aprotic and reasonably conducting at the same time, and the mechanism of conduction must be based on the mobility of Li+ cations.
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Electrochemistry in the Medium of PMMA Gel Electrolytes
Reiter, Jakub ; Vondrák, Jiří ; Sedlaříková, M. ; Velická, Jana ; Nečesal, P.
Polymer gel electrolytes are used in the electrochemistry of lithium batteries and electrochromic devices. Their investigation started in our department in 1997, when first results were published on the International Seminar on Inclusion Compounds. Investigation of electric conductivity showed, that the specific conductivity of a 0.25 M LiBF4 solution was not lowered by an addition of solid PMMA polymer more than by 40-50%. We have developed a new method preparation of gel polymer electrolyte: after a mixung of anhydrous perchlorate solution in propylencarbonate (lithium, sodium, cadmium and other sals) with monomeric and oligomeric metylmetacrylate we hawe obtained an elastic and homogenous polymer with good optical properties.
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