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Dielectric Relaxation Spectroscopy of Composite Systems
Holcman, Vladimír ; Liedermann, Karel (advisor)
The subject of this doctoral thesis is the study of dielectric properties of a binary composite made up of a polymer matrix and metallic filler. Properties of such composites have been extensively examined in the past and they turned out to depend on temperature, frequency and in particular on filler concentration. The objective of this work was first to experimentally establish and second to describe quantitatively the effect of the size of metallic particles on the properties of the composite concerned, yet at the same filler concentration. This study was carried out on the model system ethylene-vinylacetate copolymer – nickel. The acquisition of experimental results required extensive measurements in a wide frequency and temperature interval, as well as a manufacture and preparation of a large set of samples with different concentrations and Ni filler sizes. Measurements were in part carried out at the Centre for Electronic Correlations and Magnetism, Institute of Experimental Physics V of the University of Augsburg (Germany) and, after the installation of a new cryogenic system, at the Department of Physics at FEEC, BUT Brno. Measurements were performed on a number of meters (Alpha-Analyzer of Novocontrol, HP4284A and HP4285A of Hewlett Packard and E4991A of Agilent) in the frequency range 1 Hz – 1 MHz and in the temperature interval 10 K – 300 K. The nickel concentration in systems studied varied from 0 % to 75 % and nickel particles were of a spherical shape with diameters between 35 and 115 m. The measurement results have shown that in the above frequency and temperature window just a single relaxation and a single conductivity mechanism occur. It was also proved that the frequency dependence of complex permittivity is for different Ni particle sizes at the same concentration different. These results have been quantified and a simple mathematical formula based on the Lichtenecker mixture rule has been proposed for their description. The physical origin of the effect of particle size at the same total nickel concentration is sought in different surface areas of internal interfaces between nickel and polymer in the composite
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Influence of terminal groups of oligobutadiene on dielectric spectra
Vilhelm, Ondřej ; Rozsívalová, Zdenka (referee) ; Frk, Martin (advisor)
The bachelor works discourses about atributes of KRASOL LB oligobutadiens by Sartomer industries and KRASOL LB’s final groups. The research proceed by dielectric sweep spectroscopy using electrode technology Agilent 16452A that is used for gauge of transtition capacity and dissipation factor, by which we are able to enumerate both relative permittivity [‘] and figure of loss [“]. Every gauge depends on frequency and temperature.
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Dielectric properties of liquid insulators
Jahn, Michal ; Starý, Jiří (referee) ; Špinka, Jiří (advisor)
This master‘s thesis deals with measurement of liquid dielectric materials (insulators). Above all, it is the different kinds of clean and drinking water, but also transformer oils. There was done theoretical information retrieval about the given topic in this project and on the basis of theory there were realized the relevant measurements of selected properties of liquid dielectric, such as permittivity, capacitance, loss number, conductivity, but also temperature dependence of these parameters. The measurements were realized with the help of product manufactured at the faculty FEKT VUT and with the help of measuring system AGILENT 16452A. The measured results were evaluated, graphically processed and compared.
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Measurement uncertainty in diagnostics of insulating materials
Kamenická, Zuzana ; Rozsívalová, Zdenka (referee) ; Frk, Martin (advisor)
This work deals with measurement capacity and dissipation factor of capacitor with real dielectric in frequency range 20 Hz to 30 MHz. Liquid and solid dielectrics are measured by LCR instruments and by test fixtures, both from company Agilent. Relative permittivity and loss number are calculated for different instruments settings. The general aim is to specify the influence of parameters as frequency, voltage, integration time and thickness of material on the uncertainties of primary and secondary quantities for measurement.
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Multistress ageing analysis of the electroinsulating materials
Jeřábek, Michal ; Frk, Martin (referee) ; Rozsívalová, Zdenka (advisor)
This diploma thesis deals with not-aged and thermally, electric and multistress aged slotted isolations dielectric properities experimental probing. Dutiny experiment is watched influence moisture on dielectric properties insulating materiále ISONOMŽNMN. Especially both two permitivity complex components are surveyed, in dependence on the frequency and the temperature changes during thermal, electric and multistress ageing. These characteristics are viewed in light of application the isolation in practice.
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