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The content and binding of silver in galena
Němec, Matěj ; Goliáš, Viktor (advisor) ; Zachariáš, Jiří (referee)
Galena as the most important silverbearing ore is found in almost every Ag deposit. If the content of Ag is higher than 0,5 wt. % then is called galena solid solution - PbSss. The galena Ag has two forms of occurrence - inclusions and isomorphic silver. Aboat ninety percent of galena Ag is product of retrograde proces of PbSss cooling. These are matildite (AgBiS2), miargyrite (AgSbS2), diaforite (PbAg3Sb3S8), freislebenite (AgPbSbS3), pyrargyrite (Ag3SbS3) aramayoite (Ag(Sb,Bi)S2), freibergite (Ag12Sb4S13), gustavite (AgPbBi3S6) etc. The smaller amounth of isomorphic Ag is substituted as 2Ag+ = PbII+ . Under the usual conditions of deposition (200 - 300řC) , the solubility of Ag2S is to low. The content of Ag in galena under these conditions is not higher then 0,4 mol. % at 615řC. Most of the isomorphic Ag is bound in coupled substitution Ag+ + Bi III+ /Sb III+ = 2 PbII+ . In this case the content of Ag in PbS can be as high as 9 wt. % at 350 - 400řC. At the deposites where wasn't activated this Bi/Sb - Pb coupled substitution the content of Ag in galena is very low. The content of trace elements of Ag, Bi and Sb can also influence the galena crystal habit. Galena rich on Bi ususaly creates octahedral crystals. Galena with a higher content of Ag and Sb usualy creates cubic crystals.
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Radon-in-waters measurement methods
Hrušková, Lenka ; Goliáš, Viktor (advisor) ; Třískala, Zdeněk (referee)
Higher concentrations of radon are probably harmful to our health, on the other side its lower concentrations have terapeutical effect, which is used in a spa. Its characteristical properties are suitable for mineralogical research, hydrological and environmental studies and for an earthquake and vulcanic prognosis. In this work, there are explained methods of ray measuring, scintilation detektor and ionization chamber and there are compared devices like radon-in-air monitor, device with a hydrphobical membrane and device with a method using olive-oil. dtto cz.
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The vitrification methods used for the high active waste from spent nuclear fuel reprocessing.
Machová, Pavlína ; Goliáš, Viktor (advisor) ; Jelínek, Emil (referee)
This thesis summarizes the general concepts regarding the High-level waste vitrification. It describes the one-stage and two-stage principles of vitrification and special method "cold crucible". There are summarized advantages and disadvantages of these methods. In this thesis are specific of vitrification facilities around the world. There are the general characteristics of glass used for immobilization High- level waste. Most countries use borosilicate glass, but only in Russia are used phosphate glass. There is shown the composition range of glass and compare their typical properties. This thesis ends with an example of the chemical composition of certain ending vitrification products.
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Radioactive medicinal springs in the Skalná - Bad Brambach area
Turnová, Štěpánka ; Goliáš, Viktor (advisor) ; Vylita, Tomáš (referee)
Radiohydrochemical exploration took place in east part of the "smrčinský" pluton between "Skalná-Plesná-Bad Brambach in years 2016-2018. The main aim of the exploration was location and thorough research of possible occurrence of waters with radioactive concretation higher than 1500 Bq/l. That is a value for radioactive mineral waters given by the "lázeňským" law number 164/2001 Sb. Most important area is Plesná-south where was discovered several springs with values exceeding 5000 Bq/l. Eminent spring is called "Břetislav-Radonka" and lies one kilometre southwest from the train station Plesná-Šneky with an activity of about 12.5 kBq / l 222 Rn and a flow rate of about 2.5 l / min. It is the most active surface discharge of radon mineral water in the Czech Republic Another significant source area is north of Skalna - north. These springs were discovered almost 60 years ago, Dr. Marie Zukriegelová. The main source of this area was named after its discoverer - the "Marie Z" spring with an activity of 5800 Bq / l 222 Rn.Further the research focused on historical radioactive conduit which were used to supply village Skalné with water. The conduit was separated on two "branches" and the younger one was built ten years after the first one. In both pipes were found radioactive waters and the most important...
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Comparison of oxyhumolite of the Sokolov basin with materials which are using in spa and alternative medicin and its possible usage in these spheres
Dúcka, Barbora ; Rojík, Petr (advisor) ; Goliáš, Viktor (referee)
This work deal with a brief characterization of three materials, namely oxyhumolite and sapropelite from Sokolov basin that are compared with peat from Františkovy Lázně. The sampling localities are briefly geographically and geologically described including the genesis of the deposits. All materials are specifically characterized by analysis. The materials are compared based on the results of the analysis. Greater attentinon is paid to the comparison of sulfur content, humic acides and warmth retention. A part of the work is devoted to description of peloids and their influence on the human organism. The history of using peloids is briefly discussed. The possibility of using oxyhumolite and sapropelite for production of natural cosmetics or for balneological use is examined as a replacement for native and especially for regenerated peat.
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