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12M-IMMEDIATE Research Report: Preparation of Pt on Carbon Black Supported Catalysts
Kaluža, Luděk ; Zdražil, Miroslav ; Gulková, Daniela ; Vít, Zdeněk ; Šolcová, Olga ; Soukup, Karel ; Maixnerová, Lucie
The aim of this work was to elucidate on advanced preparation of Pt/C catalysts from TimCal carbon black and H2PtCl6. The attention was directed to residual content of chloride in the prepared catalysts and scale-up to the amount about 1 gram of final product. The textrual properties of the supports and selected catalyst were studied by nitrogen physisorption. The analytical methods such as instrumental neutron activation analysis (INAA), liquid ion chromatography (LC), and titration with silver nitrates were applied for Cl analysis. Electron probe micro analysis (SEM-EDX), hydrogen chemisorption, temperature programed desorption of hydrogen (TPD) and a simplified determination of ignition temperature in air flow were used for Pt/C catalysts characterization.
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Preparation of CoMo/MgO Catalysts for Hydrodesulfurization
Gulková, Daniela ; Kaluža, Luděk ; Zdražil, Miroslav ; Vít, Zdeněk
The aim of the present work was to elucidate the possibility of deposition of molybdenyland cobalt- acetylacetonates on the high surface area MgO by impregnation from solutions of these compounds in methanol. Furthermore, non-aqueous solutions of MoO3 and CoCO3, (NH4)6Mo7O24 and Co(NO3)2, MoO2(C5H7O2)2 and Co(C5H7O2)2 with chelating agent nitrilotriacetic acid (NTA) were studied for CoMo deposition in one impregnation step.
Fulltext: content.csg -  PDF
Plný tet: SKMBT_C22014082908311 - PDF
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Highly Loaded Carbon Black Supported Pt Catalysts for Fuel Cells
Kaluža, Luděk ; Zdražil, Miroslav ; Gulková, Daniela ; Vít, Zdeněk ; Šolcová, Olga ; Soukup, Karel ; Maixnerová, Lucie
The aim of this work was to elucidate on the methods of Pt deposition on carbon black to achieve high loadings of Pt of about 60 wt.% in highly dispersed form. The carbon black supports were characterized by nitrogen physisorption. Platinum was deposited on the supports: from true solutions of H2PtCl6, Pt(C5H7O2)2, Pt(NH3)4(NO3)2, or Pt(NH3)2(NO2)2, and from fine dispersions of Pt(C5H7O2)2, PtO2, Pt(NH3)4(OH)2. Atomic adsorption spectroscopy, AAS, and scanning electron microscopy, SEM, were used for elemental analysis and determination of Pt content. The deposited Pt species were dried, calcined or reduced and were subjected to temperature programmed reduction, TPR. After degassing at increased temperature, the Pt dispersion was determined by hydrogen chemisorption at -60 C.
Fulltext: content.csg - PDF
Plný tet: SKMBT_C22014082908313 - PDF
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