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Genetic relationships between intrusions of porphyry dykes and formation of Au ores at Petrov and Bohuliby
Petrov, Ivan ; Zachariáš, Jiří (advisor) ; Slobodník, Marek (referee)
This master's thesis is focused on genetic relationships between Au-bearing ores and associated granodiorite porphyry dykes in Petrov and Bohuliby area in southwestern part of the Jílové ore district. Subvolcanic rocks with hydrothermally induced alteration and Au/bearing mineralization were characterized by petrography, mineralogy and crystallochemistry. Mutual genetic and textural relationships of studied materials were examined as well and were validated by biotite, arsenopyrite and chlorite empirical geothermometry. First identified generation of sulfide mineralization was formed at 360řC and consist of arsenopyrite, galenite and native gold. At circa 274řC porphyry mineral association was chloritized, and chlorite gangue crystallized. Second generation of sulfide mineralization precipitated at 264řC. Anomalous absence of Bi-Te-S phases and scheelite in hydrothermal paragenesis is important indicator of contrasting conditions of mineralization at the studied areas and main zone of the Jílové ore deposit. Based on acquired data, granodiorite porphyry dikes were categorized to two separate genetic types, which have mutual origin in deep magma chamber of Central Bohemian Plutonic Complex but intruded non-contemporaneously.
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Metallogeny of selected gold deposits of the Bohemian Massif
Němec, Matěj ; Zachariáš, Jiří (advisor) ; Slobodník, Marek (referee) ; Sejkora, Jiří (referee)
The overall text was processed on the bases of two separate articles published recently by the author and collective, and one more article, which is currently submitted for editorial. All the articles in full are attached at the end of this work. First article is trying to decipher the evolution of formation of the Sb-Au deposits Krásná Hora-Milešov, and Příčovy. The second article is in very detail dedicated to transition of gold to aurostibite and formation of Au-Ag-Sb(S) phases at Krásná Hora-Milešov Sb-Au deposit. The third article is looking into genesis of the Voltýřov Au deposit. The Krásná Hora-Milešov and Příčovy deposits are examples of in the Bohemian Massif unique Sb-Au deposits. The deposits consist of vein type mineralization and ore is represented by massive to disseminated stibnite and disseminated gold postdating stibnite. The quartz gangue vein system is developed in Těchnice granodiorite, within robust E-W trending fault zone, and in close association with same oriented repeatedly tectonically rejuvenated lamprophyre dikes. The fluid inclusions (FI) study suggested formation of stibnite at ~250 to ~130 řC and gold at about ~200 to ~130 řC from low salinity aqueous fluids. The bulk of quartz precipitated from the same type of fluid. Disseminated arsenopyrite along with early quartz...
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Genetic relationships between intrusions of porphyry dykes and formation of Au ores at Petrov and Bohuliby
Petrov, Ivan ; Zachariáš, Jiří (advisor) ; Slobodník, Marek (referee)
This master's thesis is focused on genetic relationships between Au-bearing ores and associated granodiorite porphyry dykes in Petrov and Bohuliby area in southwestern part of the Jílové ore district. Subvolcanic rocks with hydrothermally induced alteration and Au/bearing mineralization were characterized by petrography, mineralogy and crystallochemistry. Mutual genetic and textural relationships of studied materials were examined as well and were validated by biotite, arsenopyrite and chlorite empirical geothermometry. First identified generation of sulfide mineralization was formed at 360řC and consist of arsenopyrite, galenite and native gold. At circa 274řC porphyry mineral association was chloritized, and chlorite gangue crystallized. Second generation of sulfide mineralization precipitated at 264řC. Based on acquired data, granodiorite porphyry dikes were categorized to two separate genetic types, which have mutual origin in deep magma chamber of Central Bohemian Plutonic Complex but intruded non-contemporaneously.
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Variscan fluids of the Barrandian Lower Paleozoic: case study from the Žák's quarry at Velká Chuchle
Stárková, Petra ; Zachariáš, Jiří (advisor) ; Slobodník, Marek (referee)
Hydrothermal veins in the Paleozoic of the Barrrandian testify for fluid migration during diagenesis and/or epigenesis. A more detailed mineralogical and geochemical research of these veins has started since the end of the 20th century. The subject of a research included in this thesis is determination of conditions of formation of syntectonic calcite and quartz-calcite veins in the lokality called Žák's quarry in Velká Chuchle. This thesis is based on field determination of succession of hydrothermal veins and laboratory study of fluid inclusions in minerals as a basic tool for determination of temperatures during formation of veins. In total, there were distinguished four types/generations of calcite and quartz-calcite veins in Žák's quarry (from oldest to youngest): 1) veins of ,,beef calcite", 2) veins with flat crystals of smoky quartz located in joints perpendicular to bedding, 3) shear veins with calcite located in the big fold, 4) a big calcite vein with tectonic striae spatially bound to significant local fault. Veins have thickness aproximatelly from 1 mm to about 15 cm. By the way, veins of ,,beef calcite" are characteristic by orientation of prolonged grains of calcite in the direction orthogonal towards to the plane of vein. The microscopic study of fluid inclusions revealed presence of...
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Conditions of formation of selected hydrothermal vein deposits in central part of the Bohemian Massif
Ulmanová, Jana ; Zachariáš, Jiří (advisor) ; Slobodník, Marek (referee)
This thesis deals with fluid inclusion study of quartz samples from Ratibořské Hory and Stará Vožice and baryte samples from Stříbrná Skalice and Černé Voděrady. Samples were studied by methods of microthermometry of fluid inclusions, Raman spectrometry, UV-fluorescence spectrometry and EDX analysis. In quartz sample from Stará Vožice there were detected low-salinity H2O-CO2-N2 fluids that were trapped at min. 240 MPa and 260 řC. This mineralization is probably connected with initial stages of structural evolution of the Blanice Graben. Late-metamorphic fluids were probable source of these solutions. In sample of quartz containing grains of galena there were trapped mesothermal (Th = 110-195 řC) low- to medium-salinity H2O-NaCl fluids, hydrocarbon fluids and low- salinity (H2O)-CO2-N2-CH4 fluids (containing max. 13 mol. % N2+CH4 in carbonic phase) trapped at low pressure (max. 10 MPa) and relatively low temperature (105-120 řC). In Ratibořské Hory there were detected heterogeneously trapped low- to medium-salinity H2O±CO2±N2±CH4- NaCl±KCl±MgCl2±FeCl2 (with max. 26 mol. % N2+CH4 in carbonic phase) fluids trapped at 1-25 MPa and 160-315 řC. In barite sample from Černé Voděrady were detected low- to high-salinity aqueous fluids with Na and Ca ± K, Fe, Mg chlorides. These solutions are probably derived...
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Variscan fluids of the Barrandian Lower Paleozoic: case study from the Žák's quarry at Velká Chuchle
Stárková, Petra ; Zachariáš, Jiří (advisor) ; Slobodník, Marek (referee)
Hydrothermal veins in the Paleozoic of the Barrrandian testify for fluid migration during diagenesis and/or epigenesis. A more detailed mineralogical and geochemical research of these veins has started since the end of the 20th century. The subject of a research included in this thesis is determination of conditions of formation of syntectonic calcite and quartz-calcite veins in the lokality called Žák's quarry in Velká Chuchle. This thesis is based on field determination of succession of hydrothermal veins and laboratory study of fluid inclusions in minerals as a basic tool for determination of temperatures during formation of veins. In total, there were distinguished four types/generations of calcite and quartz-calcite veins in Žák's quarry (from oldest to youngest): 1) veins of ,,beef calcite", 2) veins with flat crystals of smoky quartz located in joints perpendicular to bedding, 3) shear veins with calcite located in the big fold, 4) a big calcite vein with tectonic striae spatially bound to significant local fault. Veins have thickness aproximatelly from 1 mm to about 15 cm. By the way, veins of ,,beef calcite" are characteristic by orientation of prolonged grains of calcite in the direction orthogonal towards to the plane of vein. The microscopic study of fluid inclusions revealed presence of...
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