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Usability of stillage from ethanol production
Audy, Dan ; Večeř, Marek (referee) ; Leštinský, Pavel (advisor)
This work solves the use of stillage from ethanol production. Also solves processing into material DDGS and then solves the material and energy balance. This material and energy balance was calculated for 7070 kg of stillage per hour. The final energy requirements of the process were based on the amount of stillage produced to obtain 1 m3 of ethanol. The results of this work offer an insight to the problems of processing stillage. Thanks to conversion for 1 m3 of produced ethanol, results is also offerring the possibility of fast conversion of an approximate energy needed for devices of other capacities.
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Cleaning of biogas by the PSA (pressure swing adsorption)
Navrátil, Petr ; Houdková, Lucie (referee) ; Leštinský, Pavel (advisor)
The topic of this master thesis is upgrading of biogas. As a mixture of gases produced during anaerobic digestion, contains methane which is highly energy valuable gas. But also other substances that we want to remove. We will present the motivation for upgrading biogas and the possibility of separation, generally the pressure swing adsorption method. The key parameter of this technique is the choice of a suitable adsorbent. This is possible based on the knowledge of adsorption processes, therefore, is also described below. The objective of this thesis is to determine the parameters of the pressure swing adsorption metod. To do this it is necessary to determine the adsorption capacity of the adsorbent, measure breakthrough curves of carbon dioxide and methane, and determine the pressure drop of solid bed, etc. As a result we can finally make a balance and evaluate the applicability in practice.
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Energy consumption of equipressure and various pressures technical alcohol distillation
Audy, Dan ; Leštinský, Pavel (referee) ; Smejkal, Quido (advisor)
This hork compares the heat consumption of two units for the production of technical alcohol. The aim is to compare ordinary arrangement of rectifying distillery with an alternative arrangement, based on a modified pressure device profile. The first unit is based on the classic arrangement brewhouse, working at atmospheric pressure. The alternative unit works with different pressures in columns. In this case, the pressures are chosen so that it was possible to use heat from the head of overpressure rectification column for reboiler of vacuum mash column. The principle of pressure differences between the two columns and appropriate choice for this difference also allows the beneficial use of surplus heat. It also reduces the risk of clinkering incrusts in reboiler mash column because this works at lower temperatures than the mash column atmospheric embodiment. The comparisons of the media in this work are: The amount of steam used for reboilers of both columns, the amount of cooling water used for condensation and cooling of process streams. Furthermore, an approximate estimate of electricity consumption for pumps and other machinery. For both units is considered the same amount of mash and the same amount of product of comparable quality. The product was a technical alcohol 96.4% aa at a temperature of 25 ° C.
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Equipment for Disposal of Waste Gases of Catalytic Oxidation
Brummer, Vladimír ; Martinec, Jan (referee) ; Leštinský, Pavel (referee) ; Bébar, Ladislav (advisor)
This thesis deals with the design of the equipment and documentation for the design of equipment for the removal of volatile organic compounds (VOC) and carbon monoxide (CO) by catalytic oxidation and the selection of appropriate technological conditions for this technology. Introduction is devoted to familiarization with the field of the catalytic oxidation, used catalysts, catalyst supports and their active components. Advantages and disadvantages of the use of catalytic oxidation versus thermal incineration are outlined and currently applicable legislative terms for VOC and CO emissions are listed. In the next part of the thesis the fundamental mathematical tools and research findings available for catalytic reactor model designed primarily for monolithic catalysts are summarized. Presented kinetic model considers continuous reactor with plug flow of gas and adiabatic heating by oxidation reactions corrected for the heat loss of the reactor. The next chapter discusses the design of the new prototype of the catalytic oxidation pilot plant (i.e. the reactor incl. peripherals) primarily intended for monolithic catalysts and bulk catalysts in the form of the fixed bed. The basis for the design and sizing are material and energy balances in the ChemCAD for different intended use of the unit, from which boundary conditions of the unit operating parameters arises. Pilot plant has been designed and built, functionality tests was scheduled also with consecutive obtaining of experimental data not only for the reactor kinetic model. Results of the model for the catalytic combustion were in good agreement with measured data. The next part includes two industrial case studies of the catalytic oxidation process usage for the chemical industry. In particular it was dealt with a replacement of the non-catalytic combustion for the catalytic for VOC abatement from chemical production plants off-gas streams of the company Momentive Specialty Chemicals in Sokolov and German city Leuna. These case studies have brought many valuable experimental and technological knowledge from long-term pilot tests and also verification of design concept, thanks to which it was later possible to design a pilot unit for removal of pollutants in premises of NETME Centre and among other to economically evaluate the usage of catalytic oxidation for the off gas cleaning, in comparison with traditional combustion, in two completely different individual cases. This information was valuable and necessary for the verification of theoretical assumptions of the thesis on specific conditions of two different industrial productions. Based on acquired practical experience and theoretical background, guidelines for designing of devices for VOC and CO removal in the industry were developed.
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Equipment for Disposal of Waste Gases of Catalytic Oxidation
Brummer, Vladimír ; Martinec, Jan (referee) ; Leštinský, Pavel (referee) ; Bébar, Ladislav (advisor)
This thesis deals with the design of the equipment and documentation for the design of equipment for the removal of volatile organic compounds (VOC) and carbon monoxide (CO) by catalytic oxidation and the selection of appropriate technological conditions for this technology. Introduction is devoted to familiarization with the field of the catalytic oxidation, used catalysts, catalyst supports and their active components. Advantages and disadvantages of the use of catalytic oxidation versus thermal incineration are outlined and currently applicable legislative terms for VOC and CO emissions are listed. In the next part of the thesis the fundamental mathematical tools and research findings available for catalytic reactor model designed primarily for monolithic catalysts are summarized. Presented kinetic model considers continuous reactor with plug flow of gas and adiabatic heating by oxidation reactions corrected for the heat loss of the reactor. The next chapter discusses the design of the new prototype of the catalytic oxidation pilot plant (i.e. the reactor incl. peripherals) primarily intended for monolithic catalysts and bulk catalysts in the form of the fixed bed. The basis for the design and sizing are material and energy balances in the ChemCAD for different intended use of the unit, from which boundary conditions of the unit operating parameters arises. Pilot plant has been designed and built, functionality tests was scheduled also with consecutive obtaining of experimental data not only for the reactor kinetic model. Results of the model for the catalytic combustion were in good agreement with measured data. The next part includes two industrial case studies of the catalytic oxidation process usage for the chemical industry. In particular it was dealt with a replacement of the non-catalytic combustion for the catalytic for VOC abatement from chemical production plants off-gas streams of the company Momentive Specialty Chemicals in Sokolov and German city Leuna. These case studies have brought many valuable experimental and technological knowledge from long-term pilot tests and also verification of design concept, thanks to which it was later possible to design a pilot unit for removal of pollutants in premises of NETME Centre and among other to economically evaluate the usage of catalytic oxidation for the off gas cleaning, in comparison with traditional combustion, in two completely different individual cases. This information was valuable and necessary for the verification of theoretical assumptions of the thesis on specific conditions of two different industrial productions. Based on acquired practical experience and theoretical background, guidelines for designing of devices for VOC and CO removal in the industry were developed.
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Cleaning of biogas by the PSA (pressure swing adsorption)
Navrátil, Petr ; Houdková, Lucie (referee) ; Leštinský, Pavel (advisor)
The topic of this master thesis is upgrading of biogas. As a mixture of gases produced during anaerobic digestion, contains methane which is highly energy valuable gas. But also other substances that we want to remove. We will present the motivation for upgrading biogas and the possibility of separation, generally the pressure swing adsorption method. The key parameter of this technique is the choice of a suitable adsorbent. This is possible based on the knowledge of adsorption processes, therefore, is also described below. The objective of this thesis is to determine the parameters of the pressure swing adsorption metod. To do this it is necessary to determine the adsorption capacity of the adsorbent, measure breakthrough curves of carbon dioxide and methane, and determine the pressure drop of solid bed, etc. As a result we can finally make a balance and evaluate the applicability in practice.
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Usability of stillage from ethanol production
Audy, Dan ; Večeř, Marek (referee) ; Leštinský, Pavel (advisor)
This work solves the use of stillage from ethanol production. Also solves processing into material DDGS and then solves the material and energy balance. This material and energy balance was calculated for 7070 kg of stillage per hour. The final energy requirements of the process were based on the amount of stillage produced to obtain 1 m3 of ethanol. The results of this work offer an insight to the problems of processing stillage. Thanks to conversion for 1 m3 of produced ethanol, results is also offerring the possibility of fast conversion of an approximate energy needed for devices of other capacities.
|
|
|
Energy consumption of equipressure and various pressures technical alcohol distillation
Audy, Dan ; Leštinský, Pavel (referee) ; Smejkal, Quido (advisor)
This hork compares the heat consumption of two units for the production of technical alcohol. The aim is to compare ordinary arrangement of rectifying distillery with an alternative arrangement, based on a modified pressure device profile. The first unit is based on the classic arrangement brewhouse, working at atmospheric pressure. The alternative unit works with different pressures in columns. In this case, the pressures are chosen so that it was possible to use heat from the head of overpressure rectification column for reboiler of vacuum mash column. The principle of pressure differences between the two columns and appropriate choice for this difference also allows the beneficial use of surplus heat. It also reduces the risk of clinkering incrusts in reboiler mash column because this works at lower temperatures than the mash column atmospheric embodiment. The comparisons of the media in this work are: The amount of steam used for reboilers of both columns, the amount of cooling water used for condensation and cooling of process streams. Furthermore, an approximate estimate of electricity consumption for pumps and other machinery. For both units is considered the same amount of mash and the same amount of product of comparable quality. The product was a technical alcohol 96.4% aa at a temperature of 25 ° C.
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