|
|
Volume changes of concrete based on reactive powder components and possibilities of their regulation with chemical admixtures
Hlaváček, Jaroslav ; Kalinová, Helena (referee) ; Opravil, Tomáš (advisor)
Very high strength of RPC allows them to an unusual extreme possibilities of their applications. Volume change (shrinkage) negatively affects their relatively broad range of applications, particularly in applications which are used for filling tubes or other components. In today's advanced time with plenty of chemical ingredients and additives on the market (such as the expansion component) could be a side effect of this largely eliminated, or removed entirely. Only some components of the expansion will be appropriate for RPC cements. This reaserch investigates the expansion of ingredients on the basis of sulfates and monitors not only volume changes, but also the strength characteristics and tolerability of the tested anchors tested with a matrix component of the expansion.
|
|
|
Sol-gel synthesis of a LAS glass ceramics and influence of additives on a phase transformation and crystallization.
Kalinová, Helena ; Opravil, Tomáš (referee) ; Ptáček, Petr (advisor)
Course of synthesis of Li2O – Al2O3 – SiO2 (LAS) ceramic via sol – gel process made precursor was investigated. Powder precursor containing LAS components in molar ratio 1:1:4 were prepared by polycondensation technique in aqueous medium using lithium chloride (LiCl), hydrated aluminium nitrate (Al(NO3)39H2O) and silica sol (tosil), respectively. Heated sol was transformed into gel. The resulting gel was dried at temperature 105 °C and xerogel was next calcinated at 750°C. Further was evaluated influence of sintering additives (MgO, ZnO, Ca5(PO4)3OH) on the length of sintering interval. All of them have been stabilized spodumene in the solid solution. The properties of ceramic body prepared by sintering of precursor and grinded Li2CO2, Al2O3 a SiO2 powders were compared. Simultaneous thermogravimety and differential thermal analysis (TG-DTA), X-ray diffractions and heating microscopy were used to study sintering process of LAS ceramic.
|
|
|
Sol-gel synthesis of a LAS glass ceramics and influence of additives on a phase transformation and crystallization.
Kalinová, Helena ; Opravil, Tomáš (referee) ; Ptáček, Petr (advisor)
Course of synthesis of Li2O – Al2O3 – SiO2 (LAS) ceramic via sol – gel process made precursor was investigated. Powder precursor containing LAS components in molar ratio 1:1:4 were prepared by polycondensation technique in aqueous medium using lithium chloride (LiCl), hydrated aluminium nitrate (Al(NO3)39H2O) and silica sol (tosil), respectively. Heated sol was transformed into gel. The resulting gel was dried at temperature 105 °C and xerogel was next calcinated at 750°C. Further was evaluated influence of sintering additives (MgO, ZnO, Ca5(PO4)3OH) on the length of sintering interval. All of them have been stabilized spodumene in the solid solution. The properties of ceramic body prepared by sintering of precursor and grinded Li2CO2, Al2O3 a SiO2 powders were compared. Simultaneous thermogravimety and differential thermal analysis (TG-DTA), X-ray diffractions and heating microscopy were used to study sintering process of LAS ceramic.
|
|
|
Volume changes of concrete based on reactive powder components and possibilities of their regulation with chemical admixtures
Hlaváček, Jaroslav ; Kalinová, Helena (referee) ; Opravil, Tomáš (advisor)
Very high strength of RPC allows them to an unusual extreme possibilities of their applications. Volume change (shrinkage) negatively affects their relatively broad range of applications, particularly in applications which are used for filling tubes or other components. In today's advanced time with plenty of chemical ingredients and additives on the market (such as the expansion component) could be a side effect of this largely eliminated, or removed entirely. Only some components of the expansion will be appropriate for RPC cements. This reaserch investigates the expansion of ingredients on the basis of sulfates and monitors not only volume changes, but also the strength characteristics and tolerability of the tested anchors tested with a matrix component of the expansion.
|
guest ::
RSS feed.