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Study of interaction between engineering barriers of deep repository of spent nuclear fuel and radioactive waste
Podojil, Adam ; Jelínek, Emil (advisor) ; Kozlovcev, Petr (referee)
The thesis describes the different types of radioactive wastes (RAW), it present classification used in Czech Republic (classification of RAW isn't unified but vary according to the needs of the region for which is created. Trend of recent years in RAW disposal aimed at building a deep repositories in suitable geological formations. So it is in Czech Republic where it is planned to build repository in granitic rocks similar to the Swedish model KBS-3V/KBS-3H. This model is based on multi-barrier system which serves to maintain radionuclides outside the environment for at least 100,000 years. The system consist of engineered barriers (waste form, storage overpack, bentonite and cement) and natural barriers (rock environment in the vicinity of deep depository (near field, far field)). Study of interactions of various barriers is an important factor in the development of appropriate forms of final storage. The interactions at interface bentonite-corrosion products of container and cement- bentonite are important in terms of functionality barriers over time. In the long run, there are many changes in the properties of the individual interacting barriers. At the interface bentonite-steel shell of the container when progressing corrosion occurs to the formation of secondary minerals (magnetite, siderite,...
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Properties of cementitious matrix in the environment of radioactive waste respositories
Podojil, Adam ; Jelínek, Emil (advisor) ; Kozlovcev, Petr (referee)
Cementitious materials will serve as a construction and filler material for the construction of a deep repository of radioactive waste. Therefore, three different materials represented by four samples were studied in the present work. This is CEM II AS 42,5R cement commercially available in Čížkovice, cement CEM III B / 32,5 SV with ash and aggregate used as filler concrete for storage chambers from radioactive waste repository Richard and cement CEM I 42, 5 with fine and coarseraggregate used for fixed radioactive waste (RAW) in Velké Zbytky in the area of ÚJV Řež,as Chemical (silicate analysis) and phase composition (XRD powder diffraction analysis) were determined in the studied materials. Further, the orientation strength of the monolithic samples and their mutual comparison (compression strength measurement) were determined. Percolation leaching experiments were carried out, three columns with CEMII, RICHARD and ÚJV samples were run. The conditions of the experiments were chosen to approach the conditions in the rock environment of a possible deep radioactive waste repository. Synthetic granite water (SGW) was used as the leaching solution. In all column experiments, attempts to observe changesin the concentrations of selectedindicators (Na+ , K+ , OH- ,Ca2+ ,pH, Conductivity, SiO2, Mg2+ and...
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Study of interaction between engineering barriers of deep repository of spent nuclear fuel and radioactive waste
Podojil, Adam ; Jelínek, Emil (advisor) ; Kozlovcev, Petr (referee)
The thesis describes the different types of radioactive wastes (RAW), it present classification used in Czech Republic (classification of RAW isn't unified but vary according to the needs of the region for which is created. Trend of recent years in RAW disposal aimed at building a deep repositories in suitable geological formations. So it is in Czech Republic where it is planned to build repository in granitic rocks similar to the Swedish model KBS-3V/KBS-3H. This model is based on multi-barrier system which serves to maintain radionuclides outside the environment for at least 100,000 years. The system consist of engineered barriers (waste form, storage overpack, bentonite and cement) and natural barriers (rock environment in the vicinity of deep depository (near field, far field)). Study of interactions of various barriers is an important factor in the development of appropriate forms of final storage. The interactions at interface bentonite-corrosion products of container and cement- bentonite are important in terms of functionality barriers over time. In the long run, there are many changes in the properties of the individual interacting barriers. At the interface bentonite-steel shell of the container when progressing corrosion occurs to the formation of secondary minerals (magnetite, siderite,...
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