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Spin-trapping of radical products of H-transfer from carboneous donors
Krkošková, Petra ; Polovka, Martin (referee) ; Omelka, Ladislav (advisor)
On example of special type of a coumarine derivatives and also compounds with character of esters and diesters, which have an –CHR- group between two carbonyl groups or between carbonyl and imino group, the possibility of detection of C-radicals resulting from the homolytic splitting of the C-H bond of a methylene group was studied. PbO2 was used as an appropriate compound, on which surface the coumarine derivatives and the other compounds are decomposed. C-radicals were investigated by means of technique of spin-trapping and by comparison of experimental and simulated EPR spectra.

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