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National Repository of Grey Literature 1 records found  Search took 0.00 seconds. 
Electrochemical investigation of intramolecular electronic interactions in substituted nitrobenzens
 Liška, A. ; Ludvík, Jiří
This research represents the first part of the electrochemical study of nitrocalixarenes. The title compounds represent thus the "monomeric" fragments and their models. The electrochemical reduction of aromatic nitrocompounds in non-aqueous media proceeds generally in two steps: one-electron reversible formation of radical anion and three-electron reduction to the hydroxylamine. In this work, however, four other different mechanisms of electroreduction of aromatic nitrocompounds are presented and the influence od p-substituents on the reduction pattern are discussed.
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