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The redistribution of carbon and manganese in weldments of manganese steels
Král, Lubomír ; Zlámal, B. ; Million, Bořivoj
In this paper, the results of diffusion C and Mn measurements in diffusion couples in steels with content of manganese in range 0-15 wt.% are discussed. The diffusion and thermodynamics characteristics were evaluated by using stationary model (SM). The ratio n does not agree with condition of quasistationary model (QSM) n=2 for solution of diffusion in these diffusion couples. In the paper, the results of carbon redistribution for n=2 a n= 2,8-3,7 for diffusion couples shown above are confronted each other. The part of this paper attend to more detailed description of structure changes on weldments interface in diffusion couples 0.28C-0.04Mn/0.31C- 5.01Mn a 0.28C-0.04Mn/0.34C-15.04Mn (wt.%).
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Vzájemná difúze v systému Mg/Mg17Al12
Rothová, Věra ; Čermák, Jiří
Light Mg-based alloys are perspective materials for automotive industry. The presence of the brittle phase Mg17Al12 in the structure of the materials causes, however, certain problems in their production and during the application. It is known that desirable mechanic parameters can be easily achieved by a special annealing which leads to a less-harmful morphology of Mg17Al12 phase. The physical background of the process consists in the diffusion-controlled redistribution of components in the alloy. In the present work, the interdiffusion coefficients were measured in diffusion couples made of Mg and Mg17Al12. The results may contribute to an optimization of production process.
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A new method of estimation of diffusion characteristics in ternary systems
Čermák, Jiří ; Rothová, Věra ; Gazda, Aleš
A method was proposed based on an estimation of components of diffusion matrix, Dij, in ternary systems. It makes possible to obtain the concentration dependence of DijŽs in a wide range of concentrations using one diffusion couple only. It is in contrast to the conventional procedure that needs two diffusion couples and provides DijŽs for a single composition related to an intersection of diffusion paths. The method was applied to gammaŽ one-phase interdiffusion in Ni3Al-X (X = Cr, Fe, Nb, Ti) in temperature interval 1173 ů 1533 K.
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Comparison of Al/Ni and Co/Ni Interdiffusion Coefficients in Pseudobinary Sections of Ni3Al-Co alloys
Gazda, Aleš ; Rothová, Věra ; Čermák, Jiří
Interdiffusion in Ni3Al intermetallic alloyed by 0 - 19 at % Co was studied in three pseudo-binary sections: c(Al) = 22, c(Co) = 3.5, and c(Co) = 16 (c in at. %). The experiments were carried out at temperatures between 900 and 1200°C. Since no detectable shift of tungsten inert markers was observed, it was concluded that the intrinsic diffusivities of element pairs with varying concentration (Al/Ni and Co/Ni) in respective pseudo-binary sections are approximately equal one to another. The interdiffusion in pseudo-binary alloys Al/Ni (c(Co) = const.) runs slightly faster than that in pseudo-binary alloys Ni/Co (c(Al) = const.). The relations between the measured interdiffusion coefficients in the Ni3Al-Co ordered gamma prime phase agree well with literature data for the interdiffusion coefficients in both pure gamma prime and Co alloyed gamma prime phases and also for the disordered Al-Ni and Co-Ni solid solutions. They are qualitatively explained by interaction between constituents and/or by their interaction with vacancies.
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