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A detailed study on aerosol particle size distribution in indoor and outdoor environments with attention to ammonium nitrate transormations
Talbot, Nicholas Philip ; Ždímal, Vladimír (advisor) ; Hovorka, Jan (referee) ; Vojtíšek, Michal (referee)
Due to its prevalence over large, densely populated areas, ammonium nitrate is an important chemical species in aerosol research. However, due to its volatility at ambient temperatures and over low temperature gradients, ammonium nitrate can be a difficult species to accurately measure. The volatility of ammonium nitrate is known to be dependent on temperature, relative humidity, the internal mixing state of the particle, and availability of the precursor gas constituents. The particle's physical state affects the equilibrium constant value of the ammonium nitrate - nitric acid / ammonia exchange and helps determine the dissociation rate. For indoor aerosol research, the outdoor originating aerosol particles' exposure to the new physical conditions indoors, such as changes in temperature, humidity, and particle-surface reactions within the microenvironment all accelerate ammonium nitrate dissociation. This increased rate of partitioning can generate artifacts on datasets, increase indoor particle formation, and accelerate the corrosion of cultural antiquities through acidification. The magnitude of these impacts is uncertain due to the current lack of knowledge on particle transformation processes when outdoor originating particles migrate indoors. To address this gap in knowledge, this thesis...
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A Kitchen Degreaser Containing Monoethanolamine Can Alter Indoor Aerosol Composition for Days.
Schwarz, Jaroslav ; Makeš, Otakar ; Ondráček, Jakub ; Cusack, Michael ; Talbot, Nicholas ; Vodička, Petr ; Kubelová, Lucie ; Ždímal, Vladimír
Using of such degreaser and consequences related to indoor aerosol are described in this study. Monoethanolamine, a part of a commercial degreaser being used in kitchens, was able to replace ammonium in its sulfate and nitrate salts in the indoor environment, while those salts usually form up to half of PM2.5 aerosol mass indoors.
Fulltext: content.csg -  PDF
Plný tet: SKMBT_C22017103110530 - PDF
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A detailed study on aerosol particle size distribution in indoor and outdoor environments with attention to ammonium nitrate transormations
Talbot, Nicholas Philip ; Ždímal, Vladimír (advisor) ; Hovorka, Jan (referee) ; Vojtíšek, Michal (referee)
Due to its prevalence over large, densely populated areas, ammonium nitrate is an important chemical species in aerosol research. However, due to its volatility at ambient temperatures and over low temperature gradients, ammonium nitrate can be a difficult species to accurately measure. The volatility of ammonium nitrate is known to be dependent on temperature, relative humidity, the internal mixing state of the particle, and availability of the precursor gas constituents. The particle's physical state affects the equilibrium constant value of the ammonium nitrate - nitric acid / ammonia exchange and helps determine the dissociation rate. For indoor aerosol research, the outdoor originating aerosol particles' exposure to the new physical conditions indoors, such as changes in temperature, humidity, and particle-surface reactions within the microenvironment all accelerate ammonium nitrate dissociation. This increased rate of partitioning can generate artifacts on datasets, increase indoor particle formation, and accelerate the corrosion of cultural antiquities through acidification. The magnitude of these impacts is uncertain due to the current lack of knowledge on particle transformation processes when outdoor originating particles migrate indoors. To address this gap in knowledge, this thesis...
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Variability of Aerosols and Chemical Composition of PM10, PM2.5 and PM1 on the Platform of the Prague Underground Metro
Cusack, Michael ; Talbot, Nicholas ; Ondráček, Jakub ; Minguillon, M.-C. ; Schwarz, Jaroslav ; Otáhal, P. ; Klouda, K. ; Ždímal, Vladimír
The aim of this study is to describe aerosol concentrations and variability, and chemically characterise PM sampled during a 24 hour period on a platform of the Prague underground metro system. To this end, PM and particle number concentration and size distribution are described, and the chemical composition of PM in various size fractions is discussed, both for periods when the metro was out of operation and operational.
Fulltext: content.csg - PDF
Plný tet: SKMBT_C22014102013562 - PDF
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