|
|
Thermophysical and electrical properties of illite-based ceramics
Csáki, Štefan ; Dobroň, Patrik (advisor) ; Koštial, Pavol (referee) ; Labaš, Vladimír (referee)
CSÁKI, Štefan: Thermophysical and electrical properties of illite-based ceramics. [Doctoral thesis]. Constantine the Philosopher University in Nitra. Faculty of Natural Sciences. Charles University. Faculty of Mathematics and Physics. Supervisor: prof. RNDr. Libor Vozár, CSc. (Constantine the Philosopher University in Nitra), doc. Ing. Patrik Dobroň, PhD. (Charles University). Nitra & Prague, 2018. 107 p. Illitic clays are of special importance in the ceramic industry. Therefore, a deep knowledge of the thermophysical processes, as well as the electric properties, is of special importance. The illitic clay originated in Northeastern Hungary was used in this thesis. The reactions, occurring during firing, were studied using thermal analyses (Differential thermal analysis, Thermogravimetry, Thermodilatometry) and special attention was paid to the measurement of the electrical conductivity (both DC and AC). Up to 250 řC, where the removal of the physically bond water (PBW) takes place, the dominant charge carriers were the H+ and OH- ions. After the PBW was removed, Na+ and K+ ions became the dominant charge carriers. During dehydroxylation (450 - 750 řC) H+ and OH- ions were freed from the illite structure, which supported the electrical conduction in the samples. At ~ 970 řC glassy phase appeared...
|
|
|
Mechanical and thermophysical properties of illite-based ceramic materials.
Kušnír, Jakub ; Knapek, Michal (advisor) ; Chmelík, František (referee)
Title: Mechanical and thermophysical properties of illite-based ceramic materials. Author: Jakub Kušnír Department: Department of Physics of Materials Supervisor: RNDr. Michal Knapek, Ph.D, Department of Physics of Materials Abstract: This work examines high purity illite-based ceramic material (illite) with varying porosity, illite with fly-ash addition and textured illite- and kaolin-based ceramics. Investigated illitic clay originated from the Tokaj region in Hungary and contained 84 wt.% of illite. Kaolinitic clay (Sedlecký Kaolin Inc.) contained 88-94 wt.% of kaolinite. Samples were prepared using different heating regimes based on the type of material, with maximum firing temperature of 1100 řC. The porosity was controlled by adding charcoal powder to the green body before firing. Fly-ash waste from the combustion of powdered oil shale from Estonia was used as another additive. The microstructure of samples was analyzed by scanning electron microscopy. Mechanical properties were studied by compression tests with concurrent application of advanced investigation methods: Acoustic emission (AE) and Digital image correlation. By means of thermal analyses and AE we also investigated the frost resistance of samples with porosity created by charcoal combustion. Keywords: illite; kaolinite; ceramics;...
|
|
|
Thermophysical and electrical properties of illite-based ceramics
Csáki, Štefan ; Dobroň, Patrik (advisor)
CSÁKI, Štefan: Thermophysical and electrical properties of illite-based ceramics. [Doctoral thesis]. Constantine the Philosopher University in Nitra. Faculty of Natural Sciences. Charles University. Faculty of Mathematics and Physics. Supervisor: prof. RNDr. Libor Vozár, CSc. (Constantine the Philosopher University in Nitra), doc. Ing. Patrik Dobroň, PhD. (Charles University). Nitra & Prague, 2018. 107 p. Illitic clays are of special importance in the ceramic industry. Therefore, a deep knowledge of the thermophysical processes, as well as the electric properties, is of special importance. The illitic clay originated in Northeastern Hungary was used in this thesis. The reactions, occurring during firing, were studied using thermal analyses (Differential thermal analysis, Thermogravimetry, Thermodilatometry) and special attention was paid to the measurement of the electrical conductivity (both DC and AC). Up to 250 řC, where the removal of the physically bond water (PBW) takes place, the dominant charge carriers were the H+ and OH- ions. After the PBW was removed, Na+ and K+ ions became the dominant charge carriers. During dehydroxylation (450 - 750 řC) H+ and OH- ions were freed from the illite structure, which supported the electrical conduction in the samples. At ~ 970 řC glassy phase appeared...
|
|
|
Thermophysical and electrical properties of illite-based ceramics
Csáki, Štefan ; Dobroň, Patrik (advisor)
CSÁKI, Štefan: Thermophysical and electrical properties of illite-based ceramics. [Doctoral thesis]. Constantine the Philosopher University in Nitra. Faculty of Natural Sciences. Charles University. Faculty of Mathematics and Physics. Supervisor: prof. RNDr. Libor Vozár, CSc. (Constantine the Philosopher University in Nitra), doc. Ing. Patrik Dobroň, PhD. (Charles University). Nitra & Prague, 2018. 107 p. Illitic clays are of special importance in the ceramic industry. Therefore, a deep knowledge of the thermophysical processes, as well as the electric properties, is of special importance. The illitic clay originated in Northeastern Hungary was used in this thesis. The reactions, occurring during firing, were studied using thermal analyses (Differential thermal analysis, Thermogravimetry, Thermodilatometry) and special attention was paid to the measurement of the electrical conductivity (both DC and AC). Up to 250 řC, where the removal of the physically bond water (PBW) takes place, the dominant charge carriers were the H+ and OH- ions. After the PBW was removed, Na+ and K+ ions became the dominant charge carriers. During dehydroxylation (450 - 750 řC) H+ and OH- ions were freed from the illite structure, which supported the electrical conduction in the samples. At ~ 970 řC glassy phase appeared...
|
|
|
Thermophysical and electrical properties of illite-based ceramics
Csáki, Štefan ; Dobroň, Patrik (advisor) ; Koštial, Pavol (referee) ; Labaš, Vladimír (referee)
CSÁKI, Štefan: Thermophysical and electrical properties of illite-based ceramics. [Doctoral thesis]. Constantine the Philosopher University in Nitra. Faculty of Natural Sciences. Charles University. Faculty of Mathematics and Physics. Supervisor: prof. RNDr. Libor Vozár, CSc. (Constantine the Philosopher University in Nitra), doc. Ing. Patrik Dobroň, PhD. (Charles University). Nitra & Prague, 2018. 107 p. Illitic clays are of special importance in the ceramic industry. Therefore, a deep knowledge of the thermophysical processes, as well as the electric properties, is of special importance. The illitic clay originated in Northeastern Hungary was used in this thesis. The reactions, occurring during firing, were studied using thermal analyses (Differential thermal analysis, Thermogravimetry, Thermodilatometry) and special attention was paid to the measurement of the electrical conductivity (both DC and AC). Up to 250 řC, where the removal of the physically bond water (PBW) takes place, the dominant charge carriers were the H+ and OH- ions. After the PBW was removed, Na+ and K+ ions became the dominant charge carriers. During dehydroxylation (450 - 750 řC) H+ and OH- ions were freed from the illite structure, which supported the electrical conduction in the samples. At ~ 970 řC glassy phase appeared...
|
|
|
Mechanical and thermophysical properties of illite-based ceramic materials.
Kušnír, Jakub ; Knapek, Michal (advisor) ; Chmelík, František (referee)
Title: Mechanical and thermophysical properties of illite-based ceramic materials. Author: Jakub Kušnír Department: Department of Physics of Materials Supervisor: RNDr. Michal Knapek, Ph.D, Department of Physics of Materials Abstract: This work examines high purity illite-based ceramic material (illite) with varying porosity, illite with fly-ash addition and textured illite- and kaolin-based ceramics. Investigated illitic clay originated from the Tokaj region in Hungary and contained 84 wt.% of illite. Kaolinitic clay (Sedlecký Kaolin Inc.) contained 88-94 wt.% of kaolinite. Samples were prepared using different heating regimes based on the type of material, with maximum firing temperature of 1100 řC. The porosity was controlled by adding charcoal powder to the green body before firing. Fly-ash waste from the combustion of powdered oil shale from Estonia was used as another additive. The microstructure of samples was analyzed by scanning electron microscopy. Mechanical properties were studied by compression tests with concurrent application of advanced investigation methods: Acoustic emission (AE) and Digital image correlation. By means of thermal analyses and AE we also investigated the frost resistance of samples with porosity created by charcoal combustion. Keywords: illite; kaolinite; ceramics;...
|
guest ::
