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Liquid aprotic electrolytes with TiO2 a Al2O3 nanoparticles
Tomeš, Petr ; Krejza, Ondřej (referee) ; Sedlaříková, Marie (advisor)
The first part of this diploma thesis is dealing with conductivity of liquid electrolytes. The second part is about third generation gel electrolytes and thein conductivity. The electrolytes were inorganic salts LiClO4, LiBF4 and NaClO4 in an aprotic propylene carbonate (PC) -used as a solvent. Nanosized Al2O3 and TiO2 particles were, proportionally to the sample's volume, added to the both – blend and gel samples in an amount expressed by weight percentage (wt). Both liquid and gel electrolytes contained following amount on nanosorbent: 3,46% wt, 7,17% wt, 10,0% wt and 12,0% wt. The liquid electrolytes were gelled using commercially available precursor Superacryl (Spofa dental s.r.o.).
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The Freezing Point Determination Of Electrolytes With Fire Retardant By Cryoscopy Method
Štulák, Stanislav ; Vondrák, Jiří (referee) ; Máca, Josef (advisor)
The thesis is devoted to the field of properties investigation of new types of electrolytes, and assess the appropriateness of electrolytes studied in this paper for use in Li -ion batteries. It focuses specifically on electrolytes based on aprotic solvents and their mixtures with the flame retardants. The goal of the thesis is to investigate the effects of FRAs on electrolyte mixtures via changes in specific conductivity and freezing point. These objectives were fulfilled by using electrochemical impedance spectroscopy in combination with a cryoscopic measurement method. There were overall 16 samples examined. The samples were prepared as a combination of chemicals, specifically Ethylene carbonate (EC), propylene carbonate (PC), dimethyl carbonate (DMC), dimethyl sulfone (DMSO2), triethyl phosphate (TEP) Dimethyl methylphosphonate (DMMP), triphenyl phosphate (TPP). Based on the results of the experiments, the mixtures were sorted according to the observed properties in the tables listed in the last part of this paper. These values can be further used to supplement the continuing research of electrolytes and also as assistance in searching for the new electrolyte mixtures.
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Aprotic electrolytes with fire retardant
Hlava, Kamil ; Máca, Josef (referee) ; Sedlaříková, Marie (advisor)
This thesis deals with liquid aprotic electrolytes based on sulfolane with added flame retardant. The theoretical part of the thesis explains concepts - mainly aprotic electrolytes, flame retardants, and their practical use. It also discusses lithium - ion accumulators and materials used in them while focusing on the electrolyte function. The practical part of the thesis aims to measure the properties of aprotic electrolytes: their conductivity, potential window and flashpoint. It also contains a review of the measurement results.
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Liquid Electrolytes for Lithium-Ion Batteries with Enhance Fire Safety
Máca, Josef ; Paidar,, Martin (referee) ; Studničková, Marie (referee) ; Sedlaříková, Marie (advisor)
Dissertation thesis is focused on study of liquid electrolytes for lithium ion batteries. The electrical and physical properties of aprotic electrolytes are observed. The main goal is to increase the fire safety of the batteries. An anhydrous solvents and there blends was investigated. The common used solvents mixtures and new low flammable solvents were used. The common used solvents were used propylene carbonate, ethylene carbonate and others. The new solvents were sulfolane and dimethyl sulfone. In the second part of the work the phosphor base flame retardants as additive in electrolytes was investigated. The last part deals with ionic liquids and there possible use as electrolyte in lithium ion batteries.
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Liquid Electrolytes for Lithium-Ion Batteries with Enhance Fire Safety
Máca, Josef ; Paidar,, Martin (referee) ; Studničková, Marie (referee) ; Sedlaříková, Marie (advisor)
Dissertation thesis is focused on study of liquid electrolytes for lithium ion batteries. The electrical and physical properties of aprotic electrolytes are observed. The main goal is to increase the fire safety of the batteries. An anhydrous solvents and there blends was investigated. The common used solvents mixtures and new low flammable solvents were used. The common used solvents were used propylene carbonate, ethylene carbonate and others. The new solvents were sulfolane and dimethyl sulfone. In the second part of the work the phosphor base flame retardants as additive in electrolytes was investigated. The last part deals with ionic liquids and there possible use as electrolyte in lithium ion batteries.
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Aprotic electrolytes with fire retardant
Hlava, Kamil ; Máca, Josef (referee) ; Sedlaříková, Marie (advisor)
This thesis deals with liquid aprotic electrolytes based on sulfolane with added flame retardant. The theoretical part of the thesis explains concepts - mainly aprotic electrolytes, flame retardants, and their practical use. It also discusses lithium - ion accumulators and materials used in them while focusing on the electrolyte function. The practical part of the thesis aims to measure the properties of aprotic electrolytes: their conductivity, potential window and flashpoint. It also contains a review of the measurement results.
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The Freezing Point Determination Of Electrolytes With Fire Retardant By Cryoscopy Method
Štulák, Stanislav ; Vondrák, Jiří (referee) ; Máca, Josef (advisor)
The thesis is devoted to the field of properties investigation of new types of electrolytes, and assess the appropriateness of electrolytes studied in this paper for use in Li -ion batteries. It focuses specifically on electrolytes based on aprotic solvents and their mixtures with the flame retardants. The goal of the thesis is to investigate the effects of FRAs on electrolyte mixtures via changes in specific conductivity and freezing point. These objectives were fulfilled by using electrochemical impedance spectroscopy in combination with a cryoscopic measurement method. There were overall 16 samples examined. The samples were prepared as a combination of chemicals, specifically Ethylene carbonate (EC), propylene carbonate (PC), dimethyl carbonate (DMC), dimethyl sulfone (DMSO2), triethyl phosphate (TEP) Dimethyl methylphosphonate (DMMP), triphenyl phosphate (TPP). Based on the results of the experiments, the mixtures were sorted according to the observed properties in the tables listed in the last part of this paper. These values can be further used to supplement the continuing research of electrolytes and also as assistance in searching for the new electrolyte mixtures.
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|
|
Liquid aprotic electrolytes with TiO2 a Al2O3 nanoparticles
Tomeš, Petr ; Krejza, Ondřej (referee) ; Sedlaříková, Marie (advisor)
The first part of this diploma thesis is dealing with conductivity of liquid electrolytes. The second part is about third generation gel electrolytes and thein conductivity. The electrolytes were inorganic salts LiClO4, LiBF4 and NaClO4 in an aprotic propylene carbonate (PC) -used as a solvent. Nanosized Al2O3 and TiO2 particles were, proportionally to the sample's volume, added to the both – blend and gel samples in an amount expressed by weight percentage (wt). Both liquid and gel electrolytes contained following amount on nanosorbent: 3,46% wt, 7,17% wt, 10,0% wt and 12,0% wt. The liquid electrolytes were gelled using commercially available precursor Superacryl (Spofa dental s.r.o.).
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