National Repository of Grey Literature 1 records found  Search took 0.01 seconds. 
Production of singlet oxygen by metal-organic frameworks
Ondrušová, Soňa ; Lang, Kamil (advisor) ; Kubíček, Vojtěch (referee)
In the presented thesis, metal-organic framework (MOF) PCN-222 was post-synthetically modified with diphenylphosphinic acid. The parent PCN-222 and modified MOFs were characterized by powder X-ray diffractions and nitrogen adsorption isotherms. The presence of bound diphenylphosphinic acid in the modified MOFs was documented by inductively coupled plasma optical emission spectrometry, infrared spectroscopy, and 13 C and 31 P solid- state NMR. The modified MOFs have greater water-drying stability and up to four times higher singlet oxygen productivity under visible light irradiation than the parent PCN-222. Keywords: metal-organic framework, porphyrin, post-synthetic modifications, diphenylphosphinic acid, singlet oxygen, stability

Interested in being notified about new results for this query?
Subscribe to the RSS feed.