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Krystalové inženýrství nových materialů pro nelineární optiku
Fridrichová, Michaela ; Němec, Ivan (advisor) ; Černošek, Zdeněk (referee) ; Schwendt, Peter (referee)
This thesis focuses on preparation of novel compounds suitable for nonlinear optics (NLO). In particular, the target property is the second harmonic generation (SHG) and the group of interest are salts of the cations with delocalized electrons which can serve as carriers of the NLO properties. In particular, four derivatives of the highly interesting molecule of guanidine were selected and their NLO potential was proven by quantum chemical computations. In total, twenty new structures were described and those with the noncentrosymmetric structure assembly were examined for the SHG efficiency. Four of the prepared compounds exhibited a noticeable SHG efficiency, two of them even comparable to urea. The most promising compound, the guanylurea hydrogen phosphite (GUHP), was examined in more detail while many interesting NLO properties were revealed. The results of this work are presented also in 10 attached publications which are an integral part of the thesis. Keywords: nonlinear optics, second harmonic generation, guanidine derivatives, guanylurea, N-phenylbiguanide, N,N-dimethylbiguanide, N,N,N˝-triphenylguanidine
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