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Effect of heat treatments on the microstructure and hardness of high-entropy alloy
Jesenská, Mária Ľudmila ; Adam, Ondřej (referee) ; Moravčíková de Almeida Gouvea, Larissa (advisor)
V tejto práci je študovaná neekviatomická Al0.2Co1.5CrFeNi1.5Ti vysoko entropická zliatina, ktorá bola vyrobená pomocou vákuového indukčného tavenia. Zliatina v odliatom stave bola analyzovaná a tepelne spracovaná pri teplote 1000 °C po dobu 5h, a následne podrobená tepelnému spracovaniu pri teplote 750 °C po dobu ďalších 5h, s cieľom skúmania vplyvu teploty a doby tepelného spracovania na fázové zloženie, mikroštruktúru a mechanické vlastnosti. Na vyhodnotenie možných fáz prítomných v zliatine bol použitý pseudobinárny fázový diagram (CALPHAD). Mikroštruktúra zliatin bola charakterizovaná a chemicky analyzovaná pomocou röntgenovej difrakcie (XRD), elektrónovej mikroskopie (SEM) a energeticky disperznej spektroskopie. Výsledné vyhodnotenie tvrdosti materiálu prebehlo pomocou skúšok mikrotvrdosti a nanoindentácie.
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The influence of mechanical alloying on contamination of powder mixtures and bulk materials
Kubíček, Antonín ; Hadraba, Hynek (referee) ; Moravčík, Igor (advisor)
This thesis deals with the influence of process parameters on the contamination level of powder materials produced by mechanical alloying (MA) technology. For this purpose austenitic stainless steel 316 L and equiatomic CoCrFeNi high-entropy alloy (HEA) were prepared by high-energy ball milling. Both materials were milled in argon and nitrogen atmospheres from 5 to 30 hours. Spark plasma sintering method (SPS) was then used for consolidation of chosen powder samples. Chemical analysis of contamination within MA was carried out using combustion analysers for determination of carbon, oxygen, and nitrogen contents after different lengths of milling. Also differences in chemical composition of powder and corresponding bulk samples were measured. The microstructure analysis using scanning electron microscopy (SEM) of both powder and bulk materials was executed with focus on oxide and carbide presence and dispersion. Increasing content of carbon with increasing milling time was observed across all measured samples. This contamination is attributed to using milling vial made of tool steel AISI D2 (containing 1,55 wt. % of carbon). Increase of carbon content within consolidation using SPS was also observed. Milling of specimens using N2 as milling atmosphere caused higher contamination level in both AISI 316 L and HEA compared to milling in argon.
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Effect of heat treatments on the microstructure and hardness of high-entropy alloy
Jesenská, Mária Ľudmila ; Adam, Ondřej (referee) ; Moravčíková de Almeida Gouvea, Larissa (advisor)
V tejto práci je študovaná neekviatomická Al0.2Co1.5CrFeNi1.5Ti vysoko entropická zliatina, ktorá bola vyrobená pomocou vákuového indukčného tavenia. Zliatina v odliatom stave bola analyzovaná a tepelne spracovaná pri teplote 1000 °C po dobu 5h, a následne podrobená tepelnému spracovaniu pri teplote 750 °C po dobu ďalších 5h, s cieľom skúmania vplyvu teploty a doby tepelného spracovania na fázové zloženie, mikroštruktúru a mechanické vlastnosti. Na vyhodnotenie možných fáz prítomných v zliatine bol použitý pseudobinárny fázový diagram (CALPHAD). Mikroštruktúra zliatin bola charakterizovaná a chemicky analyzovaná pomocou röntgenovej difrakcie (XRD), elektrónovej mikroskopie (SEM) a energeticky disperznej spektroskopie. Výsledné vyhodnotenie tvrdosti materiálu prebehlo pomocou skúšok mikrotvrdosti a nanoindentácie.
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The influence of mechanical alloying on contamination of powder mixtures and bulk materials
Kubíček, Antonín ; Hadraba, Hynek (referee) ; Moravčík, Igor (advisor)
This thesis deals with the influence of process parameters on the contamination level of powder materials produced by mechanical alloying (MA) technology. For this purpose austenitic stainless steel 316 L and equiatomic CoCrFeNi high-entropy alloy (HEA) were prepared by high-energy ball milling. Both materials were milled in argon and nitrogen atmospheres from 5 to 30 hours. Spark plasma sintering method (SPS) was then used for consolidation of chosen powder samples. Chemical analysis of contamination within MA was carried out using combustion analysers for determination of carbon, oxygen, and nitrogen contents after different lengths of milling. Also differences in chemical composition of powder and corresponding bulk samples were measured. The microstructure analysis using scanning electron microscopy (SEM) of both powder and bulk materials was executed with focus on oxide and carbide presence and dispersion. Increasing content of carbon with increasing milling time was observed across all measured samples. This contamination is attributed to using milling vial made of tool steel AISI D2 (containing 1,55 wt. % of carbon). Increase of carbon content within consolidation using SPS was also observed. Milling of specimens using N2 as milling atmosphere caused higher contamination level in both AISI 316 L and HEA compared to milling in argon.
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