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Corrosion degradation of magnesium alloys in SBF solutions
Ročňáková, Ivana ; Horynová, Miroslava (referee) ; Doležalová Weissmannová, Helena (advisor)
Nowadays, magnesium alloys are used in many sectors of human activity, particularly in the aerospace and automotive industries, due to a combination of good mechanical properties and low density of magnesium. Recently, however, the attention is paid to the possibility of using magnesium alloys in the medical field, mainly due to the chemical properties of magnesium. The diploma thesis is focused on evaluating of the corrosion behavior of AZ31alloy and AZ61 alloys in SBF solutions that are solutions simulating body fluids. The alloys were subjected to immersion test in Hank’s solutions for time span from 24 to 1008 hours. The corrosion process was evaluated based on several factors: alloy composition, time and pH changes. The thesis also describes in detail the methodology for establishing magnesium and zinc by method of flame absorption spektrometry (F AAS). The determination of aluminum was carried out by atomic absorption spectrometry with electrothermal atomization (ET AAS).
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Determination of heavy metals in waste energetic materials with using sequential extraction
Kořínková, Alena ; Sommer, Lumír (referee) ; Doležalová Weissmannová, Helena (advisor)
Tato diplomová práce pojednává o stanovení vybraných kovů v energetických odpadech, jako je úletový popílek, škvára, struska, ložový popel, produkt odsíření apod., které pocházejí ze čtyř moravských tepláren. Extrakce kovů z energetických materiálů byla provedena Tessierovou extrakcí. Za tímto účelem byla použita extrakční činidla chlorid hořečnatý (MgCl2), octan sodný (CH3COONa), hydroxylamin hydrochlorid v kyselině octové (NH2OH.HCl v CH3COOH), peroxid vodíku v kyselině dusičné (H2O2 v HNO3) a kyselina fluorovodíková (HF). Extrakce probíhala při teplotách 25°C a 40°C. Ve všech frakcích byly stanoveny olovo, měď a kadmium s využitím atomové absorpční spektrometrie (F AAS, ET AAS) a rtuť metodou AMA 254.
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Assessment the impact of the application of excavated sediments from the dam Luhačovice on the content of risk elements in arable soil
Kratěnová, Pavla ; Komendová, Renata (referee) ; Řezáčová, Veronika (advisor)
This diploma thesis focuses on an issue concerning an excavated sediment application on an arable soil and its impact on the soil quality based on a particular case of a deposition of the sediment from the dam Luhačovice on an adjacent agricultural area. The theoretical part of this thesis is focused on a soil and sediment characteristics and functions, contained risk elements, sampling methods, determination possibilities of particular risk elements and a description of conditions which emerged from a need for the deposition of sediment obtained during scavenging of the dam Luhačovice. In the experimental part was described the process of sampling, samples processing and determining of concentration values for chosen risk elements (Cd, Cu, Hg, Ni, Pb) using flame or electrothermal atomic absorption spectrometry methods. This part also contains an evaluation of obtained results and a validation of an approval for the sediment deposition.
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The heavy metal contamination of selected sites in Ostrava
Mihočová, Silvie ; Pavlovský, Jiří (referee) ; Doležalová Weissmannová, Helena (advisor)
This thesis is focused on the assessment of contamination of non-agricultural soils of selected locations in Ostrava of hazardous metals. Selection of locations was based on the stationary pollution source REZZO1. Total 36 collected samples from 12 locations in three times periods between July 2010 and March 2011 that each collection represented a different time period for characteristic emissions conditions. The risk of metals mercury, cadmium, lead, copper and chromium were determined by atomic absorption spectrometry (F AAS, ET AAS, AMA 254).The influence of the distance of locations from stationary sources of REZZO1 on the extent of soil contamination by selected metals was confirmed.
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Assessment the impact of the application of excavated sediments from the dam Luhačovice on the content of risk elements in arable soil
Kratěnová, Pavla ; Komendová, Renata (referee) ; Řezáčová, Veronika (advisor)
This diploma thesis focuses on an issue concerning an excavated sediment application on an arable soil and its impact on the soil quality based on a particular case of a deposition of the sediment from the dam Luhačovice on an adjacent agricultural area. The theoretical part of this thesis is focused on a soil and sediment characteristics and functions, contained risk elements, sampling methods, determination possibilities of particular risk elements and a description of conditions which emerged from a need for the deposition of sediment obtained during scavenging of the dam Luhačovice. In the experimental part was described the process of sampling, samples processing and determining of concentration values for chosen risk elements (Cd, Cu, Hg, Ni, Pb) using flame or electrothermal atomic absorption spectrometry methods. This part also contains an evaluation of obtained results and a validation of an approval for the sediment deposition.
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Corrosion degradation of magnesium alloys in SBF solutions
Ročňáková, Ivana ; Horynová, Miroslava (referee) ; Doležalová Weissmannová, Helena (advisor)
Nowadays, magnesium alloys are used in many sectors of human activity, particularly in the aerospace and automotive industries, due to a combination of good mechanical properties and low density of magnesium. Recently, however, the attention is paid to the possibility of using magnesium alloys in the medical field, mainly due to the chemical properties of magnesium. The diploma thesis is focused on evaluating of the corrosion behavior of AZ31alloy and AZ61 alloys in SBF solutions that are solutions simulating body fluids. The alloys were subjected to immersion test in Hank’s solutions for time span from 24 to 1008 hours. The corrosion process was evaluated based on several factors: alloy composition, time and pH changes. The thesis also describes in detail the methodology for establishing magnesium and zinc by method of flame absorption spektrometry (F AAS). The determination of aluminum was carried out by atomic absorption spectrometry with electrothermal atomization (ET AAS).
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Determination of heavy metals in waste energetic materials with using sequential extraction
Kořínková, Alena ; Sommer, Lumír (referee) ; Doležalová Weissmannová, Helena (advisor)
Tato diplomová práce pojednává o stanovení vybraných kovů v energetických odpadech, jako je úletový popílek, škvára, struska, ložový popel, produkt odsíření apod., které pocházejí ze čtyř moravských tepláren. Extrakce kovů z energetických materiálů byla provedena Tessierovou extrakcí. Za tímto účelem byla použita extrakční činidla chlorid hořečnatý (MgCl2), octan sodný (CH3COONa), hydroxylamin hydrochlorid v kyselině octové (NH2OH.HCl v CH3COOH), peroxid vodíku v kyselině dusičné (H2O2 v HNO3) a kyselina fluorovodíková (HF). Extrakce probíhala při teplotách 25°C a 40°C. Ve všech frakcích byly stanoveny olovo, měď a kadmium s využitím atomové absorpční spektrometrie (F AAS, ET AAS) a rtuť metodou AMA 254.
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|
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The heavy metal contamination of selected sites in Ostrava
Mihočová, Silvie ; Pavlovský, Jiří (referee) ; Doležalová Weissmannová, Helena (advisor)
This thesis is focused on the assessment of contamination of non-agricultural soils of selected locations in Ostrava of hazardous metals. Selection of locations was based on the stationary pollution source REZZO1. Total 36 collected samples from 12 locations in three times periods between July 2010 and March 2011 that each collection represented a different time period for characteristic emissions conditions. The risk of metals mercury, cadmium, lead, copper and chromium were determined by atomic absorption spectrometry (F AAS, ET AAS, AMA 254).The influence of the distance of locations from stationary sources of REZZO1 on the extent of soil contamination by selected metals was confirmed.
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