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Properties of cementitious matrix in the environment of radioactive waste respositories
Podojil, Adam ; Jelínek, Emil (advisor) ; Kozlovcev, Petr (referee)
Cementitious materials will serve as a construction and filler material for the construction of a deep repository of radioactive waste. Therefore, three different materials represented by four samples were studied in the present work. This is CEM II AS 42,5R cement commercially available in Čížkovice, cement CEM III B / 32,5 SV with ash and aggregate used as filler concrete for storage chambers from radioactive waste repository Richard and cement CEM I 42, 5 with fine and coarseraggregate used for fixed radioactive waste (RAW) in Velké Zbytky in the area of ÚJV Řež,as Chemical (silicate analysis) and phase composition (XRD powder diffraction analysis) were determined in the studied materials. Further, the orientation strength of the monolithic samples and their mutual comparison (compression strength measurement) were determined. Percolation leaching experiments were carried out, three columns with CEMII, RICHARD and ÚJV samples were run. The conditions of the experiments were chosen to approach the conditions in the rock environment of a possible deep radioactive waste repository. Synthetic granite water (SGW) was used as the leaching solution. In all column experiments, attempts to observe changesin the concentrations of selectedindicators (Na+ , K+ , OH- ,Ca2+ ,pH, Conductivity, SiO2, Mg2+ and...
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Experimental study of Palaeozoic limestones of the Barrandian and their possible use for burning of hydraulic limes and natural cement
Kozlovcev, Petr
54 Summary In this experimental study, selected Devonian limestones of the Prague Basin (i.e. samples from the historic quarry of Branické skály) were examined to find their suitability for production of hydraulic limes or for natural cement. Four representative samples of the dvorecko-prokopské limestone were sampled in the form of blocks weighing approximately 10 kg each, from the layer of the quarry wall that had been chosen based on literature research. A detailed mineralogical-petrographic examination of samples was the first step, in an attempt to obtain their mineralogical composition, microstructure and texture. Samples were analysed by polarizing microscopy and cathodoluminescence of thin sections, and X-ray diffraction of insoluble residues determined by treatment with both the hydrochloric acid and the acetic acid solution. Mineralogical composition of the insoluble residuals was illite, kaolinite, quartz and Na-plagioclase (albite). Two samples contained among above mentioned mineral phases also chlorite. The utility of studied limestones for the production of hydraulic binders (hydraulic limes and natural cement) was derived from both the calculations based on obtained chemical analyses (included standard cement and lime indexes and modules) and the firing experiments. The firing experiments...
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Study of interaction between engineering barriers of deep repository of spent nuclear fuel and radioactive waste
Podojil, Adam ; Jelínek, Emil (advisor) ; Kozlovcev, Petr (referee)
The thesis describes the different types of radioactive wastes (RAW), it present classification used in Czech Republic (classification of RAW isn't unified but vary according to the needs of the region for which is created. Trend of recent years in RAW disposal aimed at building a deep repositories in suitable geological formations. So it is in Czech Republic where it is planned to build repository in granitic rocks similar to the Swedish model KBS-3V/KBS-3H. This model is based on multi-barrier system which serves to maintain radionuclides outside the environment for at least 100,000 years. The system consist of engineered barriers (waste form, storage overpack, bentonite and cement) and natural barriers (rock environment in the vicinity of deep depository (near field, far field)). Study of interactions of various barriers is an important factor in the development of appropriate forms of final storage. The interactions at interface bentonite-corrosion products of container and cement- bentonite are important in terms of functionality barriers over time. In the long run, there are many changes in the properties of the individual interacting barriers. At the interface bentonite-steel shell of the container when progressing corrosion occurs to the formation of secondary minerals (magnetite, siderite,...
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Material analyses of plaster samples of the historical building named “Nové Probošství”, Pražský hrad, nám. sv. Jiří č.p. 34.
Drdácký, Miloš ; Slížková, Zuzana ; Frankeová, Dita ; Hasníková, Hana ; Hauková, Petra ; Koudelková, Veronika ; Kozlovcev, Petr ; Ševčík, Radek ; Wolf, Benjamin
The report contains the results of the material analyses of plasters and stone samples taken from the facades and interior plasters of the historical building named “Nové Probošství” (Pražský hrad, nám. sv. Jiří č.p. 34).). The topic of the study was determination of the chemical composition and the microstructure of historical plasters and renders, sandstone petrography, porosity of materials by means of MIP, water absorption of plasters by tubes, the water content and the moisture distribution in masonry wall, the content and the chemical composition of water-soluble salts in plasters and renders. The results of the study serves as the basis for the future design of the building renovation and the restoration of the artistic elements.\n
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Experimental study of Palaeozoic limestones of the Barrandian and their possible use for burning of hydraulic limes and natural cement
Kozlovcev, Petr ; Přikryl, Richard (advisor) ; Vavro, Martin (referee)
54 Summary In this experimental study, selected Devonian limestones of the Prague Basin (i.e. samples from the historic quarry of Branické skály) were examined to find their suitability for production of hydraulic limes or for natural cement. Four representative samples of the dvorecko-prokopské limestone were sampled in the form of blocks weighing approximately 10 kg each, from the layer of the quarry wall that had been chosen based on literature research. A detailed mineralogical-petrographic examination of samples was the first step, in an attempt to obtain their mineralogical composition, microstructure and texture. Samples were analysed by polarizing microscopy and cathodoluminescence of thin sections, and X-ray diffraction of insoluble residues determined by treatment with both the hydrochloric acid and the acetic acid solution. Mineralogical composition of the insoluble residuals was illite, kaolinite, quartz and Na-plagioclase (albite). Two samples contained among above mentioned mineral phases also chlorite. The utility of studied limestones for the production of hydraulic binders (hydraulic limes and natural cement) was derived from both the calculations based on obtained chemical analyses (included standard cement and lime indexes and modules) and the firing experiments. The firing experiments...
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Limestones of Český kras and their use for hydraulic limes and natural cements
Kozlovcev, Petr ; Kuchařová, Aneta (referee) ; Přikryl, Richard (advisor)
ii Summary This bachelor thesis is focused on the possible use of limestones from the Český kras area for the preparation of alternative inorganic binders, namely for hydraulic limes and natural cements. In the introductory chapters, the geology of Český kras is described. Silurian and Devonian beds make the most important lithostratigraphic members. Then, the history of limestone exploitation and processing is explained. It is followed by the petrographical characteristic of limestone - its mineralogical and chemical composition, the structure and the texture, the classification, the genesis and the diagenesis. Major part of the thesis focuses on inorganic binders - their basic characterization and evaluation. Limestones are discussed from the point of their general use in the industry. The limestones from the Český kras area are analyzed based on their chemical composition (based on the previously reported data) and evaluated for the potential use for burning of hydraulic limes and natural cements.
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Material analysis of natural stone - sedimentary and crystalline limestone ("marble") - exact laboratory methods as a tool to determine the source area
Přikryl, Richard ; Šťastná, Aneta ; Kozlovcev, Petr ; Přikrylová, Jiřina ; Zamrazilová, Lenka
Metodika se zabývá hlavními postupy a analytickými rozbory, které lze využít k petrografickému a geochemickému popisu sedimentárních vápenců a mramorů, který poté slouží k určování jejich provenience. V metodice je diskutován rozsah použití jednotlivých metod pro popis sedimentárních a krystalických vápenců („mramorů“) a současné možnosti jejich petrografické klasifikace. Předkládaná metodika je určena pro oblast památkové péče, která využívá výsledků materiálových rozborů objektů kulturního dědictví – sochařských výtvarných děl, architektonických prvků a staveb, zhotovených ze sedimentárního nebo krystalického vápence. Výsledky, dosažené pomocí postupů, navržených v této metodice by měly přispět: (1) ke zpřesnění znalostí o materiálu; (2) ke sjednocení postupů, používaných při klasifikaci vápenců a mramorů; (3) k nalezení zdrojové lokality či alespoň oblasti, z níž byl přírodní kámen (vápenec a mramor) odebírán; (4) k hledání vhodného náhradního typu vápence nebo mramoru při nutnosti výměny; (5) k poznání vhodných postupů při restaurování objektů ze sedimentárního nebo krystalické vápence. Oblast využití této metodiky je tedy při předrestaurátorských materiálových průzkumech památek, na nichž byl použit příslušný typ přírodního kamene, tedy vápenec nebo mramor. Předložená metodika je určena širšímu okruhu specialistů, kteří se podílejí na předrestaurátorských materiálových průzkumech památek, nebo rozbor zadávají, či výsledky průzkumu potřebují pro volbu vhodné strategie restaurování. Metodika byla certifikována dne 28. 5. 2015, Osvědčení č. 34(č.j. MK 3363/2015 OVV; sp. zn. MK-S 115/2015 OVV).
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