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Studium dimerů molekulárními můstky spojených stříbrných nanočástic pomocí metody SERS
Šmejkal, P. ; Vlčková, B. ; Moskovits, M. ; Pavel, I. ; Sládková, M. ; Pavlova, Ewa ; Šlouf, Miroslav
The ability of several molecules to act as linkers for Ag nanoparticles was tested. As new prospective linker molecules, dimercaptocarborane, ethidium bromide and 5,10,15,20-tetrakis(4-sulphonatophenyl)porphine (TSPP) were selected owing to their terminal functional groups, which can assemble the Ag nanoparticles together to form a dimer.
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Změny velikostí zlatých nanočástic vysokoenergetickými laserovými pulsy
Dammer, Ondřej ; Pfleger, Jiří ; Šlouf, Miroslav ; Vlčková, B.
We focused on the interaction of gold nanoparticles of various mean size embedded in aqueous environment with nanosecond pulsed laser irradiation of various energy per pulse at wavelength 355 and 532 nm, respectively. We performed a sequence of in-situ surface plasmon extinction (SPE) measurements of the fragmented hydrosol as well as ex-situ TEM studies to evaluate the size distribution of resulting Au nanoparticles. It was found that laser pulses of 355 nm wavelength provide smaller nanoparticles compared with 532 nm pulses at the same absorbed energy.
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Fotogenerace nosičů náboje v polymerních nanokompozitech
Pfleger, Jiří ; Pavlík, Martin ; Vohlídal, J.
Polymer nanocomposites seem to be promising systems for solar cell application with polythiophene acting as photosensitizer and charge transport medium. The electrophoretic deposition proved to be suitable method for preparation nanostructured core/shell functional layers. The simplicity, fast operation rate and the possibility of covering surfaces of irregular shape, as well as a good quality of prepared films are the major advantages of the method.
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Funkční polymery pro aplikace v solárních článcích
Pfleger, Jiří ; Pavlík, Martin ; Hebestreit, N. ; Plieth, W.
Two alternative systems of polymer based solar cell structures were prepared: 1) based on the acceptor modified .pi.-conjugated polymer and 2) composed of a functional polymer - inorganic semiconductor nanocomposite, and their photoelectrical properties were tested. The simple electrodeposition method, providing a large area heterojunction distributed within a bulk of the polymer nanocomposite, was developed.
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