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National Repository of Grey Literature

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IR Laser-Induced Carbothermal Reduction of Titanium Monoxide: Carbon-Phase Shield to Nanosized TiO Oxidation Jandová, Věra ; Bastl, Zdeněk ; Šubrt, Jan ; Pola, Josef Pulsed IR laser-irradiation of titanium monoxide (TiO) leads to ablation and when carried out in gaseous benzene (1-5 Torr) to simultaneous dielectric breakdown of benzene into low molecular carbonaceous species. Both processes allow carbothermal reduction of ablated TiO particles with agglomerating carbonaceous species and deposition of carbon-coated TiO nanoparticles remarkably stable towards oxidation in air. The reported results suggest potential for protection of reactive gas-phase produced nanoparticles by carbon phase. Detailed record

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