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Měření excitačních a ionizačních teplot v expandujícím proudu H2O-Ar plazmatu
Sember, Viktor ; Mašláni, Alan
Optical emission spectroscopy is used to determine the temperature in a plasma jet expanding from the H2O-Ar dc arc torch into a chamber maintained at a pressure of 10 kPa. The excitation and rotational temperatures are derived from relative intensities of argon atomic and ionic lines, and from the UV OH band at 306.357 nm, respectively. The ionization temperature is obtained from the intensity ratio of argon ionic and atomic lines, using electron number density calculated from the Stark broadening of hydrogen H line. The structure of the plasma jet is characterized by isocontours of electron number density and intensity of atomic and ionic lines. In the expansion region, the ionic excitation temperature is found close to the ionization temperature and much higher than the excitation temperature of argon atoms, which is close to the rotational temperature of OH radical. In the normal shock region, all the measured temperatures tend to be equal.
Studium expandujícího proudu termického plazmatu s využitím molekulových spekter
Mašláni, Alan ; Sember, Viktor
Thermal plasmas generated by plasma torches are well-known for their high temperatures and high enthalpies. Therefore optical emission spectroscopy is appropriate diagnostic method because of strong emission of radiation corresponding to the visible light. The decay of excited atoms, ions and molecules causes emission of the light at characteristic wavelengths. Except spectral lines of atoms and ions, also some molecular bands can be seen in the spectra of the plasma jet. Especially expanding thermal plasma jet operated under low pressure conditions offers possibility of observing molecular transitions. Pressure lower than atmospheric may cause the presence of supersonic flow and departures from thermodynamic equilibrium. Spectra of OH radical have been investigated using computer code LIFBASE, which contains a lot of data regarding spectra of diatomic molecules. Radial profiles of rotational and vibrational temperatures have been found in several regions of the jet.

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