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Li+ a H+ vodivé polymerní elektrolyty s kovalentně vázanými anionty
Reiter, Jakub ; Michálek, Jiří ; Přádný, Martin ; Chmelíková, Dana ; Širc, Jakub
New single-ion conducting electrolytes based on methacrylates were prepared using direct, radically initiated polymerisation: copolymers of methacrylic acid (MA) or lithium methacrylate (LiMA) with 2-ethoxyethyl methacrylate (EOEMA) and poly(ethylene glycol) methyl ether methacrylate (EGMEMA) as pure cationically conducting Li+ or H+ electrolytes and covalently bonded carboxylic group. For the conductivity improvement, a set of electrolytes with embedded aprotic solvent (propylene carbonate PC or N,N-dimethylformamide DMF) was prepared.
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Electrochemistry in the Medium of PMMA Gel Electrolytes
Reiter, Jakub ; Vondrák, Jiří ; Sedlaříková, M. ; Velická, Jana ; Nečesal, P.
Polymer gel electrolytes are used in the electrochemistry of lithium batteries and electrochromic devices. Their investigation started in our department in 1997, when first results were published on the International Seminar on Inclusion Compounds. Investigation of electric conductivity showed, that the specific conductivity of a 0.25 M LiBF4 solution was not lowered by an addition of solid PMMA polymer more than by 40-50%. We have developed a new method preparation of gel polymer electrolyte: after a mixung of anhydrous perchlorate solution in propylencarbonate (lithium, sodium, cadmium and other sals) with monomeric and oligomeric metylmetacrylate we hawe obtained an elastic and homogenous polymer with good optical properties.
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