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Thickness dependence of transport properties of Bi.sub.2./sub.Te.sub.3./sub. layers
Zeipl, Radek ; Lošťák, P. ; Pavelka, Martin ; Žďánský, Karel ; Jelínek, Miroslav ; Walachová, Jarmila
The transport properties of layers, prepared by laser ablation, as Hall mobility and conductivity on their thickness at room temperature are presented. This thermoelectric materials is potential candidate for many applications as for thermoelectric devices for power generation, cooling and sensors.

Thickness dependence of transport properties of Bi.sub.2./sub.Te.sub.3./sub. layers
Zeipl, Radek ; Lošťák, P. ; Pavelka, Martin ; Žďánský, Karel ; Jelínek, Miroslav ; Walachová, Jarmila
The transport properties of layers, prepared by laser ablation, as Hall mobility and conductivity on their thickness at room temperature are presented. This thermoelectric materials is potential candidate for many applications as for thermoelectric devices for power generation, cooling and sensors.

Application of Monte Carlo simulations in banking
Boruta, Matěj ; Teplý, Petr (advisor) ; Fučík, Vojtěch (referee)
Currently, banking is exposed to huge market risks. One of those risks is occurrence of negative interest rates in the EU. Nowadays, it is important to use sophisticated and modern measurement tools and approaches to measure and manage banking risks. One of those methods is Monte Carlo simulation. This bachelor thesis is aimed at analysis and prediction of 3-month maturity Prague Interest Offer Rate (PRIBOR) for 3, 6 and 12 months with using Monte Carlo simulations. It was found that this method is suitable for prediction market variables with low volatility. If anybody uses this method, it is necessity to have in mind all pitfalls and assumptions, that this method includes, as an adequate random generated number of scenarios, approximation of correct probability distribution, independence of dataset and not least, as far as possible, to focus on factors generating randomness of market variable and not the prices, that express rather consequences of randomness than its cause. Further, the Monte Carlo prediction was compared with prognosis of the Czech Nation Bank and it was found that Monte Carlo prediction is more accurate for short term predictions. 12-month prediction of Monte Carlo simulation discovered also possible occurrence of negative interest rate at 0,05% level of probability in compare to the Czech National Bank prognosis, where was no negative interest rate predicted.

Fatigue failure mechanism of nickel-based superalloy Inconel 713LC under 800°C
Smékalová, Jana ; Juliš, Martin (referee) ; Hutařová, Simona (advisor)
Nickel superalloys are used for high-temperature application in energetic and aerospace industry. They are exposed to aggressive environment at high temperatures with the interactions between fatigue and creep processes, high-temperature oxidation, corrosion and erosion. Lifetime extension of such strained parts while increasing the performance of particular machine is possible by applying protective surface coatings. The subject of this work is to investigate the fatigue failure mechanisms of superalloy Inconel 713LC at 800 °C and to compare these mechanisms between material with a protective coating based on Al-Si and material without coating. The location of initiation fatigue cracks, their propagation and the fatigue crack propagation rate in some areas were analyzed by optical microscopy, scanning electron microscopy and confocal laser scanning microscopy. Based on previous research it was found that the application of the coating AlSi has a positive effect on lifetime of alloy Inconel 713LC. These results were confirmed and estimated in the diploma thesis.

Metallic and ceramic filters for high temperature applications
Brožek, Vlastimil ; Neufuss, Karel
Tungsten, tungsten carbide, aluminium oxide, titanium oxide, zirconium silicate and tungsten silicide powders were spheroidized in water stabilized plasma. After shape-classification the microfilters were sintered by HIP and HP methods at 1800-2000°C and 150-270 MPa. The permeability, porozity, corrosive and temperature resistence and mechanical properties were tested.

Pressure influence on the magnetic and transport properties of the f-electron compounds
Míšek, Martin ; Javorský, Pavel (advisor) ; Kamarád, Jiří (referee)
In this thesis, we describe the work with a new pressure cell, its implementation in Joint Laboratory for Magnetic Studies, together with testing measurements necessary for ensuring good environmental conditions control and trouble-free operation. We have chosen a single crystal of the CePtSn compound to be the first representative measurement. We measured electrical resistivity along crystallographic b-axis in conditions: T = 2-300 K, p = 0-2.5 GPa and magnetic field B = 0-14 T applied along b-axis. We observed only minimal pressure influence on temperatures of magnetic phase transitions, however interesting and rather unusual behavior in magnetic fields was revealed. Previous works reported two field-induced transitions at low temperatures and ambient pressure, with values of the critical fields BcLF ~ 4 T and BcHF ~ 11.5 T, accompanied with large magnetoresistence step of -30% and +10%, respectively. With application of pressure, we observed shift of the critical field of low-field transition BcLF to the higher fields, whereas the value of critical field of high-field transition BcHF was unaffected with applied pressure. At a p ~ 1.5 GPa the two transitions merged and only one step was observed. With pressure further increasing above 1.5 GPa, situation with two transitions, similar to the lower pressure...

Design of a space heating system with heat pump in family house
Valešová, Jaroslava ; Charvát, Pavel (referee) ; Katolický, Jaroslav (advisor)
This master`s thesis deals with low-temperature heating that employs a heat pump. The introduction gives reasons for utilization of the renewable heat sources for heating. The next part focuses on a practical application of renewables on the heating of a family house. It covers a detailed description of the building and the designed heating system which includes: the calculation of thermal losses, design of the low-temperature boiler, heat pump, safety devices, heating elements, sizing and control of the system. The last part is devoted to the assessment of the system performance.

ELECTRON BEAM REMELTING OF PLASMA SPRAYED ALUMINA COATINGS
Matějíček, Jiří ; Veverka, J. ; Čížek, J. ; Kouřil, J.
Plasma sprayed alumina coatings find numerous applications in various fields, where they enhance the properties of the base material. Examples include thermal barriers, wear resistance, electrical insulation, and diffusion and corrosion barriers. A typical structure of plasma sprayed coatings, containing a multitude of voids and imperfectly bonded interfaces, gives them unique properties - particularly low thermal conductivity, high strain tolerance, etc. However, for certain applications such as permeation barriers or wear resistance, these voids may be detrimental.\nThis paper reports on the first experiments with remelting of plasma sprayed alumina coatings by electron beam technology, with the purpose of densifying the coatings and thereby eliminating the voids. Throughout the study, several parameters of the e-beam device were varied - beam current, traverse velocity and number of passes. The treated coatings were observed by light and electron microscopy and the thickness, structure and surface morphology of the remelted layer were determined and correlated with the process parameters. Based on the first series of experiments, the e-beam settings leading to dense and smooth remelted layer of sufficient thickness were obtained. In this layer, a change of phase composition and a marked increase in hardness were observed.\n


Bioceramic Materials for Advanced Medical Applications
Novotná, Lenka ; Lapčík,, Lubomír (referee) ; Drdlíková, Katarina (referee) ; Cihlář, Jaroslav (advisor)
Cílem disertační práce bylo připravit trojrozměrné biokeramické podpůrné systémy („skafoldy“), které by v budoucnu mohly pomoci při rekonstrukci a regeneraci poškozených kostních tkání. Porézní keramické pěny byly připraveny dvěma způsoby – replikační technikou a polymerizací in situ. Co se složení týče, byly studovány keramické materiály zejména na bázi oxidu hlinitého, zirkoničitého a kalcium fosfátů. Byl studován jednak vliv procesních parametrů jako je složení suspenzí a jejich viskozit, dále pak vliv tepelného zpracování na strukturu a výsledné vlastnosti připravených materiálů. U slinutých pěn byla pomocí rastrovací elektronové mikroskopie hodnocena zejména morfologie – velikost pórů, jejich propojenost a celková porozita, charakterizace mikrostruktury nebyla opomenuta. Dále bylo stanoveno fázové složení a pevnost v tlaku. Z biologických vlastností byla testována a diskutována bioaktivita a cytotoxicita materiálů. Disertační práce je členěna do několika částí. V literární rešerši je popsána stavba a vlastnosti kosti, požadavky kladené na kostní náhrady, výhody a nevýhody současně používaných materiálů a způsoby přípravy keramických pěn. Následuje experimentální část, kde byly nejprve studovány pěny připravené replikační technikou. Všechny takto vyrobené pěny měly propojené póry o velikostech 300 až 2000 m, celková porozita se pohybovala v rozmezí 50 – 99 %. Pevnost pěn na bázi kalcium fosfátů – 0,3 MPa (při celkové porozitě 80%) byla nedostatečná pro kostní náhrady, kde je požadována pevnost větší než 2 MPa. Kalcium fosfátové keramiky byly tedy zpevněny buďto inertním jádrem na bázi oxidu hlinitého nebo ATZ (oxidem zirkoničitým zhouževnatělým oxidem hlinitým). Dále byl přípraven částicový kompozit, ve kterým byl hydroxyapatit pojený oxidem křemičitým. Pevnost pěn se podařilo zvýšit až na více než 20 MPa. V poslední kapitole experimentální části byly studovány keramické pěny pěněné in situ, kde byly póry vytvářeny oxidem uhličitým unikajícím během reakce mezi diisokyanátem a polyalkoholem. Po vypálení polymerního pojiva měly pěny propojené póry o průměrné velikosti 80 až 550 m. Celková porozita se pohybovala v rozmezí 76 – 99%. Výhodou oproti replikační technice byly plné trámečky bez velké středové dutiny vznikající vypálením polymerní předlohy. Žádný ze studovaných materiálů nebyl pro buňky toxický, navíc všechny studované pěny vykazovaly bioaktivní chování. Z hlediska kostního tkáňového inženýrství se jako nejslibnější jeví kompozitní materiál zpevněný oxidem křemičitým.