National Repository of Grey Literature 6 records found  Search took 0.01 seconds. 
Theoretical Principles and Technologic Applications of "Copper Mediated Destruction" Method for Persistent Organic Compounds Destruction.
Ocelka, T. ; Pekárek, Vladimír
Theoretical principles of persistent organic pollutants formation by de novo synthetic reaction and destruction methods are presented. The role of copper for the these reactions is outlined. The dehalogenation / detoxification results are presented for DDT and its metabolites, chlorinated hexachlorocyclohexane and hexachlorobenzene and for polychlorinated dibenzo-p-dioxine, dibenzofurane and biphenyls.
Tall Soap - Undesirable Waste at Paper Production or Valuable Raw Material?
Rousková, Milena ; Tříska, Jan ; Heyberger, Aleš
The paper and pulp industry is due to its huge production capacity source of a big amount of waste - tall soap. This material is often utilized as a not very valuable source of energy, even though it contains many compounds applicable in the chemical, pharmaceutical, food or cosmetics industry. It comprises of a high proportion of fatty and resin acids, used as additives to grease, adhesives, resins, paints or inks. Long-chain aliphatic alcohols serve medical purposes, mainly for atherosclerosis treatment. Phytosterols belong to the most valuable substances contained in the tall soap. These compounds are being applied for hypercholesterolaemia and some types of cancer, they also have a significant therapeutic effect on the cardiovascular and immune systems. Waste tall soap is potentially a very valuable source of a broad spectrum of substances.
Pressure and Temperature Waves in Periodically Operated Hydrogenation Reactor.
Stavárek, Petr ; Jiřičný, Vladimír ; Staněk, Vladimír ; Hanika, Jiří ; Tukač, V. ; Chyba, V. ; Lederer, J. ; Kolena, J. ; Kubička, D.
Paper deals with behaviour investigation of trickle bed reactor with periodically modulated feed rate of liquid reaction mixture. Dicyclopentadiene hydrogenation using palladium supported catalyst was used as a model reaction. Feed rate modulation parameters – period length and its split – have effect on pressure and temperature waves travelling down along catalyst bed.
Pyrolysis Gasoline Hydrogenation in Trickle Bed Reactor with Periodically Modulated Feed Rate.
Tukač, V. ; Hanika, Jiří ; Chyba, V. ; Handlová, M. ; Sazanov, Z. ; Lederer, J. ; Kolena, J. ; Jiřičný, Vladimír ; Stavárek, Petr ; Staněk, Vladimír
The effect of feed rate modulation on efficiency of pilot plant trickle bed reactor during pyrolysis gasoline hydrogenation using palladium supported catalyst was investigated. Enhancement factors for unsaturated hydrocarbon components were evaluated from experiments made both in steady state and dynamic operation modes. Feed rate modulation mode prefered hydrogenation of minority components of the feed.
Internal Diffusion Effect on Styrene and Dicyclopentadiene Hydrogenation.
Sazanov, S. ; Tukač, V. ; Chyba, V. ; Handlová, M. ; Hanika, Jiří ; Lederer, J. ; Kolena, J.
Internal efficiency factors of palladium on alumina catalyst have been evaluated for hydrogenation of unsaturated hydrocarbons – styrene and dicyclopentadienene - representing key components of pyrolysis gasoline. Effect of catalyst particle diameter and temperature on reaction rate has been investigated in the study.
Process Engineering - Effective Tool for New Technics.
Hanika, Jiří ; Novák, L.
An importance of process engineering in development of new technologies is discussed in the paper. Establishment of the Czech SusChem Technology Platform and its role supporting cooperation in science, design, development for effectivity rise of chemical industry is described too.

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