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Aminocarbene complexes of Cr, W and Fe of the Fischer Type – oxidation and reduction properties, electron delocalization and intramolecular communication
 Ludvík, Jiří ; Zvěřinová, R. ; Hoskovcová, I.
Newly synthesized Cr, Fe and W aminocarbene complexes were electrochemically investigated, namely their oxidation and reduction properties. The Influence of the number of carbonyl ligands on the central metal atom was studied, as well as the difference between chelating and non-chelating ligands. Special attention has been paid to the role of the substituent in the para-position on the phenyl ring attached directly to the carbene carbon. The detailed interpretation enabled to discuss mutual intramolecular influence of redox centers in molecules.
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1 Zvěřinová, Radka
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