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Voltammetric determination of anilazine on silver solid amalgam electrode
Bystrianský, Martin ; Fischer, Jan (advisor) ; Dejmková, Hana (referee)
Anilazine (4,6-dichloro-N-(2-chlorophenyl)-1,3,5-triazin-2-amine) is a fungicide from a group of triazine pesticides. These have been very widely used but for their toxicity for water environment they are being cancelled. Use of anilazine is not allowed anymore in the European Union. However, traces of its residues are able to find in environmental samples. The diploma thesis deals with determination of anilazine using silver solid amalgam electrode modified by mercury meniscus (m-AgSAE). Differential pulse voltammetry was used. For the determination, an acidic solution is necessary. In the work Britton-Roninson buffer pH = 2 was used. This is because of electrochemical reduction of anilazine (and other triazines) which is started by protonization of heterocycle ring. Anilazine exhibits one single well-defined peak, the potential of the peak was about Ep = -827 mV (vs. 3 mol l-1 argentochloride electrode). The limit of quantification achieved in surface water was 2 µmol.l-1. Other two possibilities of getting lower limit of quantification were examined - Adsorptive Stripping Voltammetry (AdSV) and preconcentration by Solid Phase Extraction (SPE). Using AdSV the limit of quantification LQ = 0,5 µmol.l-1. Conditions of adsorption were as following: Eacc = -100 mV, tacc = 60 s. For SPE, 200-mg columns...
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Ambient ozon impact on vegetation
Bystrianský, Martin ; Hůnová, Iva (advisor) ; Čabala, Radomír (referee)
Bystrianský: Ambient ozone impact on vegetation - Abstract Ambient ozone is present in the air all around the world. It is natural component of the atmosphere, due to anthropogenic emissions of ozone precursors its concentration rise. That is unlikely, because ozone is toxic. Ozone is formed as a part of photochemical smog from ozone precursors by photochemical reactions. As ozone precursors nitrogen oxides (NOx) and volatile organic compounds (VOC) are called. Their main source is car traffic. Danger of ozone lies in its reactivity. It oxidizes most of organic compounds, especially those containing double bonds. These are present in membrane lipids. Furthermore, ozone forms more reactive compounds than itself - active oxygen species (AOS), free radicals. Ozone effects negatively both human health and vegetation. Ozone disrupts structure of the cells, which for plants means destroy of leaves and needles, photosynthesis disruption and biomass loss. For that, plants have antioxidants system for AOS scavenging. But it has little effect, when concentration of ozone is high during smog period. Therefore, limits for maximal concentration of ozone in the ambient air are set.
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