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National Repository of Grey Literature 11 records found  previous11 - 11  jump to record: Search took 0.00 seconds. 
Radical products of the oxidation of selected phenols and amines
 Holubcová, Petra ; Mazúr, Milan (referee) ; Omelka, Ladislav (advisor)
In the framework of diploma thesis, radical products of the oxidation of selected para­methyl phenols and secondary amines were investigated. In the case of para-methyl phenols using EPR spectroscopy the reaction mechanism was proved, where the abstraction of hydrogen from para-methyl group is involved. In this way benzyl radicals are formed, which can be identified by spin-trapping technique using nitroso compounds. The adducts formed undergo the consecutive rearrangement, which leads to the formation of the corresponding nitrones. In addition to phenols, the radical products of the oxidation of some secondary amines using peroxy radicals and peroxy acids were studied. In both cases new types of nitroxyle radicals were generated and the EPR parameters were determined by spectral simulation.
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National Repository of Grey Literature : 11 records found   previous11 - 11  jump to record:
See also: similar author names
1 Mazur, Michal
1 Mazúr, Miroslav
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