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Feasibility study: Hg removal technology using electrochemical methods - large unit and its comparison with alternative technology
Zach, Boleslav ; Veselý, Václav ; Šyc, Michal ; Puchýř, R. ; Foltýn, M. ; Přemyslovský, P. ; Pařízek, V.
In the introductory chapters, an introduction to the technology for Hg capture from combustion processes using electrochemical methods (membrane electrolyzer)and the design of a unit with capacity applicable to a typical power plant unit was made. This technology has not fully demonstrated its effectiveness from laboratory tests in semi-operational trials. These findings have been taken into account in the design of the unit for a larger power plant, therefore the design considers the use of more units in parallel, which places demands on the built-up space. The number of units used and the size of the built-up area is then matched by the high cost of the investment. Although this is a technology that does not consume any chemicals or sorbents - only electricity - it is an investment and operationally expensive technology, as can be seen from the comparison with alternative technologies. A comparison of the investment costs and cumulative expenditure (investment, reinvestment, maintenance and operating costs) for the electrochemical technology with electrolyzer and the two alternative technologies shows that if the economic aspect alone is the decisive criterion for the choice of technology, the technology of dosing Na2S solution into the scrubber absorber solution for flue gas treatment clearly comes out best at current prices.

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