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National Repository of Grey Literature

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Electrochemical Properties of Mixed Self-Assembled Monolayers Based on Terpyridine Transition Metal Complexes Kocábová, Jana ; Nováková Lachmanová, Štěpánka ; Vavrek, František ; Valášek, M. ; Hromadová, Magdaléna This work presents the electrochemical characterization of mixed self-assembled monolayers\n(SAMs) of [Os(terpy)2]2+ and terpyridine connected by tripodal anchoring groups to the\npolycrystalline gold bead electrode and provides a comparison with SAM based on\n[Os(terpy)2]2+ tripodal molecules without diluting terpyridine tripodal molecules. It is shown\nthat both arrangements enable reproducible preparation of well-defined compact films. The\nelectron transfer rate constant for mixed SAM was determined from cyclic voltammograms\naccording to Laviron’s analysis and compared with the rate constant obtained previously for\nSAM containing only [Os(terpy)2]2+ tripod. Detailed record

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