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Determination of crystal field parameters in selected tetragonal compounds
Zubáč, Jan ; Javorský, Pavel (advisor) ; Prchal, Jiří (referee)
The thesis deals with a crystal electric field and its effect on magnetic properties of the in- termetalic tetragonal rare-earth compounds. Using the self-flux method we have prepared single crystals of two R2TIn8 type compounds, namely Nd2RhIn8 and Nd2IrIn8. These compounds or- der antiferromagnetically in low-temperature region. We have verified a proper structure through EDX analysis, X-ray powder diffraction and Laue diffraction method. Calculations of the crystal field parametres based on experimental magnetic susceptibilities data were performed. Apart from Nd2RhIn8, we have computed crystal field parameters for isostructural Nd2CoIn8 and Dy2CoIn8 compounds and cerium compound CeCuAl3. These compounds are studied simultaneously at our department.

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