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National Repository of Grey Literature

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Luminescence in organic silicons prepared from organic precursors in plasma discharges Horváth, P. ; Schauer, F. ; Kuřitka, I. ; Salyk, O. ; Weiter, M. ; Dokoupil, N. ; Nešpůrek, Stanislav ; Fidler, V. Photoluminescence of plasma prepared the poly[methyl(phenyl)silanediyl] - during the change from linear 1D Si chain to amorphous 3D Si network was studied. The excitonic band with maximum at 353 nm in 1D Si undergoes a blue shift and broadening on introducing networking defects. With the gradual transition from 1D to 3D structure the redistribution of oscillator intensity along the absorption edge was observed. Detailed record

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