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Co-Mn-Al Spinel Catalyst for Removal of N2O from Nitric Acid Plant Tail Gases
Obalová, L. ; Karásková, K. ; Kovanda, F. ; Jirátová, Květa ; Šrámek, J. ; Kustrowski, P. ; Chromčáková, Ž. ; Kočí, K. ; Borovec, K. ; Dej, M.
Fulltext: content.csg -  PDF
Plný tet: SKMBT_C22013110615453 - PDF
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Total Oxidation of Organic Compounds in Air over Oxide Catalysts
Ludvíková, Jana ; Jirátová, Květa ; Kovanda, F. ; Klempa, Jan
The aim of this work was investigation of the influence of various combinations of metals, Cu, Co, Ni, Mn or Al on properties of LDH (layered double hydroxides)-precursors and their calcined forms, examination of formation of these layered double hydroxides on a model support (anodized aluminum foil), and determination of catalytic activity of the calcined precursors in oxidation of ethanol as model compound.
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Aktivita směsných oxidů přechodných kovů nanesených na nosič Al2O3/Al při úplné oxidaci VOC
Jirátová, Květa ; Kovanda, F. ; Klempa, Jan ; Ludvíková, Jana ; Krúpa, L. ; Gaálová, Jana
The MII-(Mn)-Al and MII-Cu-(Mn)-Al LDH precursors (MII = Ni and/or Co) were deposited on Al2O3/Al support during hydrothermal reaction in aqueous solutions containing divalent metal cations. Only a slight incorporation of Mn into deposited solid was observed. The obtained LDH films consisted of thin platelet crystals oriented nearly perpendicularly to the support; their morphology did not change even after heating at 500 °C, when mixed oxides were formed. The deposited mixed oxides containing Cu showed reduction peaks at the lowest temperatures, and, from that reason, the Cu-containing catalysts, namely the Ni-Cu-(Mn)-Al sample was the most active in the total oxidation of ethanol.
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Modifikace směsných oxidů Co-Mn-Al promotory a jejich vliv na vlastnosti a aktivitu při oxidaci VOC
Mikulová, Z. ; Jirátová, Květa ; Klempa, Jan ; Kovanda, F.
The influence of the catalysts chemical composition and of the mode of promoters incorporation on the activity and selectivity in VOC oxidation was studied. In total oxidation of toluene, the most active Co4MnAl catalysts were those containing low concentration of potassium regardless the mode of modification, while in ethanol total oxidation the catalyst impregnated with higher potassium concentration (3 wt%) was the most active. Introduction of Pt and Pd in amounts 0.5 or 0.1 wt% into the Co4MnAl catalyst did not improve its catalytic activity. The impregnation method appears to be more effective mode of catalyst modification than the method using an addition of promoters in the stage of coprecipitation of the LDH precursor.
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