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Reaction synthesis of bulk intermetallic materials from cold spray deposits from binary powders containing iron
Dyčková, Lucie ; Krajňáková, Petra (referee) ; Jan, Vít (advisor)
This thesis deals with reaction synthesis of materials Fe–Al, Fe–Cu and Fe–Ni from cold spray. In literature analysis are introduced these systems and for each system there is brief description of binary equilibrium diagram. Furthermore here are some short explanations of diffusion, Kirkendall effect and other possible processing technologies of intermetallic materials. In experimental part, samples of sprayed materials were annealed and then microstructural changes were investigated. This thesis contains photographs of microstructure, results from scanning electron microscopy, X-ray, and measurements of microhardness.
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Oxidation behavior adjustment for TiAl intermetallics by controled atmosphere surface remelting
Prehradná, Jana ; Čížek, Jan (referee) ; Jan, Vít (advisor)
Rešerše se zabývá teorií technologického způsobu zpracování materiálů, tzv. povrchového tavení. V první části rešerše je popsána samotná technologie a základní parametry ovlivňující proces tavení. Ve druhé části je uvedeno srování dvou základních typů laserů, a to Nd:YAG a CO2 laser. CO2 laser byl použit v případě našeho experimentu. Třetí část se zabývá vlastnostmi TiAl intermetalických slitin, především jejich fázemi -TiAl a -Ti3Al. Na závěr teoretické části je zmíněna oxidace TiAl intermetalických slitin. Experimentální část je věnována přetavování povrchu slitiny Ti-46Al-0,7Cr-0,1Si-7Nb-0,2Ni, a to v ochranné atmosféře dusíku. Tato část obsahuje výsledky několika experimentů, na jejichž základě bylo nutné stanovit potřebné parametry pro požadovaný proces tavení. Posledním krokem experimentu byla snaha o zvýšení hmotnosti vzorků v důsledku následné oxidace.
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Oxidation behavior adjustment for TiAl intermetallics by Al-Y multilayers
Handrk, Jiří ; Tkachenko, Serhii (referee) ; Jan, Vít (advisor)
Mechanické vlasnosti intermetalika na bázi titan hliník Ti-46Al-7Nb-0.7Cr-0.1Si-0.2Ni jsou konstatní do teploty 700 °C. Nad touto teplotou slitina oxiduje. Cílem této práce bylo zlepšit oxidační vlastnosti pomocí kovové multivrstvy na bázi yttrium hlinik. Pro depozici vrstev byla použita metoda PVD. Na vzorky byly naneseny vrstvy čistého ytria nebo kombinace yttrium, hliník. Vzorky byly následně žíhány v inertní atmosféře na 700°C a 900°C nebo nebyly. Kvalita nanesených vrstev byla zkoumána pomocí scratch testu a EDS analýzi. Dále byly vzorky izotermicky oxidovány na 900°C po dobu 100 hodin. Na vzorcích byly po oxidaci prováděny měření pevnosti v tříbodovém obybu a měření hmotnosti. Chemické složení oxidické vrstvy bylo vyhodnoceno pomocí EDS. Žádná z vrstev s nebo bez žíhání neprokázaly zlepšení oxidických vlastností. Vyšší teplota žíhání prokýzala zlepšení mechanických vlastnotí vrstvy, ale zhoršení materiálu.
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Reaction synthesis of bulk intermetallic materials from kinetic spraying deposits
Stejskal, Pavel ; Roupcová, Pavla (referee) ; Jan, Vít (advisor)
This work deals with issues of preparation of intermetallics based on iron, nickel and titanium aluminides. It works with an idea of preparation of bulk material by reaction synthe-sis from kinetic spraying deposits by cold spray. Theoretical part is concerned with phases and compounds of these aluminides for structural applications, their characteristics and present fabrication. In experimental part there are studied microstructures created by annealing of deposits.
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Surface treatment of selected steels using electron beam
Matlák, Jiří ; Jan, Vít (referee) ; Kouřil, Miloslav (advisor)
The aim of diploma thesis was preparation of hardened layer on three chosen types of materials with different alloying components content without surface melt by using electron beam technology. The influence of chosen process parameters was observed on the prepared hardened layers properties and shapes. In the first part of bibliographic search there are described electron beam properties, possibilities of his influencing and control. There is given example of complete set of electron beam are mentioned in the second part of theoretical research.
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Analysis of Iron-Phosphorus Reaction Products Formation During Heat Treatment Processes
Skoumalová, Zuzana ; Jan, Vít (referee) ; Doležal, Pavel (advisor)
During high pressure pulsation tests repeated cracks of CP3. housings occur. High pressure pump CP3 is part of injection system Common Rail. Cracks can be caused by segregation of phosphorous from a washing medium on grain boundaries during subsequent heat treatment process. The present master´s thesis focuses on analysis of phosphorous compounds on specimen surface made from steel 20MnCr5, which were soaked in solutions with different concentration of phosphorous. Master’s thesis is also focused on potencial influence of phosphorous on structure and properties of this material. The first part of the thesis provides a summary of current knowledge in the studied field, experimental results can be found in the second part. The surface analysis XPS, the light microscopy, the scanning electron microscopy equipped by energy dispersive chemical analysis, the glow discharge optical emission spectroscopy, the methods of the phase analysis by means of the X-ray diffraction and impact test were used.
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Embrittlement of TiAl intermetalics induced by surface oxidation
Fukátková, Pavla ; Jan, Vít (referee) ; Dlouhý, Ivo (advisor)
This work aimed to study the effect of surface oxidation of TiAl intermetallic alloys, its fracture behavior and study the formation and stability of picked coatings that could prevent these phenomena. ?-TiAl alloy (Ti46Al7Nb) was examined by three different coatings (AlCr, AlCrN and AlCrNAg). Firstly, it was carried out short-term exposure to high temperature in an inert atmosphere for all coatings. Secondly, there were experiments of cyclic exposure to high temperature in normal atmosphere and isothermal high-temperature exposure in a normal atmosphere. During high-temperature experiments in normal atmosphere mass gain was measured and it was monitored a surface texture. Finally, the most promising coatings were chosen, and those were evaluated in bending strength.
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Modelling of Phase Composition of Heat Resistant Steels and their Welds
Dvořáček, Ondřej ; Foret, Rudolf (referee) ; Jan, Vít (advisor)
This work deals with the effects of high temperature exposition of low alloyed creep resistant steels on their structural stability and structural stability of their weld joint. The theoretical part of this work gives an overview of creep resistant steels considering their chemical and phase composition and their connection to high temperature mechanical properties. The CALPHAD method is presented as generally accepted approach for equilibrated calculations and Thermo-Calc and DICTRA software packages are introduced as CALPHAD applications. Thermo-Calc software is used for calculation of phase composition of the examined materials and for calculation of the phase diagrams. Software DICTRA is used for simulations of diffusion controlled phase reactions in the analysed weld. Experimentally one weld joint of the steels 15 128 and 15 313 has been studied after four different annealing procedures. The experimental results include chemical profiles across the welds, microhardness profiles and metallographic analysis of significant regions of the welds. These experimental results are compared with the simulation results. The comparison shows a reasonable agreement between experimental and simulation data.
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