Název: Development of Flow-Through Electrochemical Cell RaFEC for Oxidation State Adjustment of Superheavy Elements Homologues
Autoři: Sochor, J. ; Němec, M. ; Bartl, P. ; Hrdlička, Vojtěch ; Navrátil, Tomáš ; Zach, Václav ; Štursa, Jan ; Omtvedt, J. P. ; John, J.
Typ dokumentu: Příspěvky z konference
Konference/Akce: Modern Electrochemical Methods /44./, Jetřichovice (CZ), 20250519
Rok: 2025
Jazyk: eng
Abstrakt: This paper focuses on the development of a flow-through electrochemical cell called RaFEC for adjusting the oxidation state of short-lived transcatinoid homologs in high yield and short reaction\ntime. In the first development phase, experiments were performed with thallium as nihonium (synthetic element, atomic number 113) homolog, using both long-lived 201 Tl and short-lived Tl\nradioisotopes generated on the U-120M cyclotron. The adjustment of Tl oxidation state in the flow-through cell is followed by the separation of the different oxidation states of thallium \n(Tl +I /Tl +III) by liquid-liquid extraction using Aliquat 336 in a hydrochloric acid environment. The aqueous and organic phases from the extraction were analyzed on a gamma spectrometer.
Klíčová slova: flow electrochemical cell; oxidation states adjusting; RaFEC
Číslo projektu: LM2023060 (CEP)
Poskytovatel projektu: GA MŠk
Zdrojový dokument: Proceedings of the International Conference 44th Modern Electrochemical Methods, ISBN 978-80-908947-2-3

Instituce: Ústav fyzikální chemie J. Heyrovského AV ČR (web)
Informace o dostupnosti dokumentu: Dokument je dostupný v příslušném ústavu Akademie věd ČR.
Původní záznam: https://hdl.handle.net/11104/0366925

Trvalý odkaz NUŠL: http://www.nusl.cz/ntk/nusl-679999