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Sorption Ceramic Membranes with a Functionalized Surface Layer
Zub, Yu.L. ; Tomina, V.V. ; Melnyk, I.V. ; Stolyarchuk, N.V. ; Nazarchuk, H.I. ; Sliesarenko, V.V. ; Sliesarenko, V.M. ; Topka, Pavel ; Šolcová, Olga
In the current work, we have considered and compared the deposition on the surface of ceramic membrane of the polysiloxane layers with different functional groups, such as ≡Si(CH2)3SH, ≡Si(CH2)3NH2, and ≡Si(CH2)2P(O)(OH)2, and ≡Si(CH2)3NHC(S)NHC2H5. We have also reported the fabrication of ceramic membranes with bifunctional polysiloxane surface layers, containing two types of complexing groups of different nature, or (fluoro)alkyl groups along with complexing groups. Tetraethoxysilane and bis(triethoxy)silane structuring agents were used in the study. The identification of the deposited layers on the membrane surface was carried out by IR spectroscopy. It was shown by SEM, that the functionalized layers themselves are usually formed by 50-70 nm nanoparticles and their porous structure depends on several fabrication factors.
Fulltext: content.csg -  PDF
Plný tet: SKMBT_C22014090110370 - PDF
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Samonosné pelety z (Al)-SBA-15
Topka, Pavel ; Zub, Yu.L. ; Šolcová, Olga
Self-supporting pellets were successfully formed from SBA-15 and Al-SBA-15 powder without the addition of binder or plasticizer. Prepared self-supporting pellets maintained the porous structure of original powder. In comparison with parent sample, a decrease of mesopore surface area and mesopore volume up to 40 % was noticed in the case of pellets formed with the highest 17.7 MPa pressure. The Al-SBA-15 pellets prepared using 4.7 MPa forming pressure were enough mechanically stable to retain the structural integrity during batch alkylation of toluene with benzyl alcohol at 110 °C. The conversion reached with Al-SBA-15 pellets after 60 min of the reaction was about five times lower than that accomplished with powder Al-SBA-15.
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Fyzikální metody ke stanovení struktury povrchové vrstvy funkcionalizovaných mesoporézních silik
Zub, Yu.L. ; Šolcová, Olga
The given report is an attempt to summary the results of composition and structure studying of functionalized mesoporous silicas surface. These results have been received with the help of a number of physical methods (electronic microscopy, the thermal analysis, IR and Raman spectroscopy, solid-state (CP/MAS) NMR spectroscopy (on such nucleus as 1H, 13C, 29Si, 31P), MALDI, metal microprobe method) and also quantum chemistry.
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