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National Repository of Grey Literature

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Study of the composition influence in the mixture CsCl-HfCl.sub.4./sub. on its thermal properties in enclosed system using DSC analysis Král, Robert ; Zemenová, Petra ; Vaněček, Vojtěch ; Bystřický, Aleš This contribution deals with the study of thermal behavior of CsCl-HfCl4 mixture of various composition (containing excess of Cs- or Hf-component) in enclosed system (quartz ampoule) by non-isothermal DSC analysis. Important information necessary for optimization of the Cs2HfCl6 crystal growth by the vertical Bridgman method were obtained from the comparison of the recorded results and the CsCl-HfCl4 phase diagram. Detailed record

Study of cesium hafnium chloride by methods of thermal analysis Král, Robert ; Zemenová, Petra ; Bystřický, Aleš ; Vaněček, Vojtěch ; Kohoutková, M. This work deals with the study of processes in cesium hafnium chloride (Cs2HfCl6) and its single crystal under thermal treatment by thermal analyses (different scanning calorimetry, thermogravimetry and thermomechanical analysis). Results showed thermal instability of Cs2HfCl6 and its significant decomposition to cesium and hafnium chloride above the eutectic temperature. Detailed record

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