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Characterization of fine-grained montmorillonite fractions suitable for composite preparation
Valovičová, Věra ; Vaculíková, Lenka ; Plevová, Eva ; Dolinská, S. ; Znamenáčková, I. ; Danková, Z.
The aim of this experimental study was to characterize a fine-grained fraction of montmorillonites (SAz-2, STx-1, SWy-2 and Kunipia-F). It was investigated in order to provide more precise information of used montmorillonites than could be obtained by analysis of the unfractioned montmorillonites. At first, the fine fraction of montmorillonites were prepared by sedimentation and activation by means of Na2CO3. The prepared clay materials were characterized by the X-ray diffraction analysis and FTIR spectroscopy. The thermal behaviour of the studied samples was determinated according to the characteristic temperatures obtained from TG/DTA curves. The temperatures of dehydratation and dehydroxylation were evaluated and kinetic parameters were also calculated. The porosity and surface properties of the studied samples were gained by the nitrogen adsorption measurements. The obtained results confirmed that the fine fraction of montmorillonites could be a suitable material for subsequent preparation of composites with enhanced sorption properties, especially montmorillonite/MnO2 composite.
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Application of bentonite-manganese oxide composites in removal of heavy metals
Dolinská, S. ; Znamenáčková, I. ; Tomčová, J. ; Valovičová, Věra ; Vaculíková, Lenka ; Plevová, Eva
The paper is aimed on the using of non-homogeneous bentonites coated by manganese oxides for the removal of heavy metal cations from the water solutions. In the first stage Slovak natural bentonite was converted to sodium form using by Na2CO3 as the activating agent. After that the manganese oxides were precipitated on the surface of natural and sodium activated bentonite, respectively. The structural changes before and after the modifications of bentonites were characterized by X-ray diffraction analyses and X-ray photoelectron spectroscopy. To compare the sorption properties of the natural bentonite and modified bentonites, sorption experiments of Cd2+ from aqueous solutions were done.
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