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Ceramic protection of anti-corrosion layers of 3-glycidyloxypropyl-triethoxysilane on steel
Pokorný, P. ; Janata, Marek ; Brožek, Vlastimil
There are various variations on the problem of steel reinforcement bond strength in concrete. Along with geometrical considerations, corrosion performance of steels with varying chemical compositions in interaction with variable chemical compositions of concrete are crucial. One approach is to cover steel surfaces with organosilane compounds, which increases the reinforcement resistance to corrosion in both acidic and alkaline conditions but, on the other hand, may weaken the reinforcement bond strength on concrete. The issue is resolved by intentionally forming a thin-walled, highly adhering corundum layer that is highly porous and impregnated with 3-glycidyloxypropyltriethoxysilane. This procedure also includes testing the adhesion properties between the ceramic and the metal and the cement prior to conducting a corrosion test in a chloride environment.
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Ceramic protection of anti-corrosion layers of 3-glycidyloxypropyl-triethoxysilane on steel
Pokorný, P. ; Prodanović, N. ; Janata, Marek ; Brožek, Vlastimil
There are various variations on the problem of steel reinforcement bond strength in concrete. Along with geometrical considerations, corrosion performance of steels with varying chemical compositions in interaction with variable chemical compositions of concrete are crucial. One approach is to cover steel surfaces with organosilane compounds, which increases the reinforcement resistance to corrosion in both acidic and alkaline conditions but, on the other hand, may weaken the reinforcement bond strength on concrete. The issue is resolved by intentionally forming a thin-walled, highly adhering corundum layer that is highly porous and impregnated with 3-glycidyloxypropyltriethoxysilane. This procedure also includes testing the adhesion properties between the ceramic and the metal and the cement prior to conducting a corrosion test in a chloride environment.
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Právní úprava ostrovů a umělých ostrovů z hlediska mezinárodního mořského práva
Janata, Marek ; Ondřej, Jan (vedoucí práce) ; Balaš, Vladimír (oponent)
Právní úprava ostrovů a umělých ostrovů z hlediska mezinárodního mořského práva Abstrakt Diplomová práce se zabývá historickým vývojem přirozených a umělých ostrovů a jejich zakotvení v současné právní úpravě. Další části práce jsou věnovány typologickému vydělení umělých ostrovů dle jejich možného využití a nastínění možnosti států stavět umělé ostrovy v mořských zónách. Od přijetí Úmluvy o mořském právu v roce 1982 nedošlo k významné kodifikaci či mezinárodní konferenci na toto téma. Jediným významným sporem v poslední dekádě týkající se otázek umělých ostrovů bylo arbitrážní řízení ve sporu o Jihočínské moře. První část diplomové práce se věnuje historickému vývoji právní regulace mořského práva od 15. století do současnosti. Od 20. století je věnována pozornost především názorovým proudům a návrhům týkajících se problematiky právního vymezení umělých a přirozených ostrovů. Nejdůležitějšími konferencemi 20. století, kde vyvstala otázka ostrovů, byly Haagská konference v roce 1930, První konference o mořském právu v roce 1958 a Třetí konference o mořském právu v roce 1982. Druhá část je zaměřena na právní úpravu jednotlivých mořských zón. Tato problematika je klíčová pro pochopení mořského práva obecně, ale i specifickým právním pojmům jako jsou ostrovy, skály, vynořující se vyvýšeniny a další mořské...
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Corrosion behavior of plasma coatings CuAl10 and CuAl50 on magnesium alloy AZ 91
Kubatík, Tomáš František ; Stoulil, J. ; Stehlíková, K. ; Slepička, P. ; Janata, Marek
The most common magnesium alloy AZ 91 is widely used as a structural material, but its use is limited at higher temperatures and high humidity. Plasma spraying is a technology that allows to prepare protective metallic and non-metallic coatings on a wide variety of substrates including magnesium and its alloys. In this study, CuAl10 and CuAl50 were plasma sprayed on magnesium alloy AZ 91 with the aim to study corrosion resistance of the plasma sprayed coatings. The corrosion resistance of layers was evaluated by the method of electrochemical potentiodynamic measurement as well as long-term corrosion tests in a condensation chamber with 0.5 mol\nNaCl at the temperature of 35 °C for 1344 hours. Layers with 1, 2, 5 passes and passes of CuAl10 with the thickness ranging from 75 to 716 mm and CuAl50 with the thickness ranging from 64 to 566 mm were prepared. The increased corrosion velocity was observed in the case of thin layers of 2 and 5 passes due to the development of a galvanic corrosion couple. The CuAl10 layer prepared with ten passes has an outstanding corrosion resistance.
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Mechanical and chemical properties of plasma sprayed bronze CuAl10 coating on magnesium and magnesium alloy AZ91
Kubatík, Tomáš František ; Vilémová, Monika ; Mušálek, Radek ; Janata, Marek
The most common magnesium alloy AZ91 is widely used as a structural material, but its use is limited at higher temperatures and high humidity. Plasma spraying is a technology that allows to prepare protective metallic and nonmetallic coatings on a wide variety of substrates including magnesium and its alloys. In this study, CuAl10 was plasma sprayed on magnesium and magnesium alloy AZ91 with the aim to study corrosion resistance of the magnesium substrates. The work focuses on optimization of the plasma spraying process, on chemical composition of the coatings, on interface between the coating and substrate, as well as on adhesive strength of the coatings. The coating were deposited after two passes of the spraying torch resulting in thickness of 150 micro m on magnesium substrate and 110 micro m on AZ91 substrate. Chemical microanalysis showed that deposition of CuAl10 alloy on magnesium results in formation of an intermetallic layer at the interface. The layer provides a
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Chemical aspects of antiballistic cermets preparation
Brožek, Vlastimil ; Kubatík, Tomáš František ; Chráska, Tomáš ; Mušálek, Radek ; Janata, Marek ; Mastný, L.
The paper aims to demonstrate the possibilities of metal-ceramic material deposition on different types of metal or ceramic substrates using plasma deposition. A number of self-supporting components and the preparation of metal-braced composites are described and the results of plasma depositions of two particular extremely hard ceramic materials, boride and nitride of titanium are presented. The plasma deposition of these material is performed in technological conditions which prevent undesirable high-temperature oxidation. The paper describes deposition conditions that may lead to materials suited to create anti-ballistic protection and complicated shapes or improve parameters of surface layers of present anti-ballistic ceramics.
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