National Repository of Grey Literature 16 records found  1 - 10next  jump to record: Search took 0.01 seconds. 
Metastable alloy Ti-15Mo prepared by powder metallurgy
Veverková, Anna ; Bartha, Kristina (advisor) ; Chráska, Tomáš (referee)
This diploma thesis focused on manufacturing and characterization of Ti-15Mo metastable beta-Ti alloy prepared by cryogenic milling and spark plasma sintering. Initial powder was prepared by gas atomization and consequently deformed by cryogenic milling (milled powder). Both initial and milled powders were compacted by spark plasma sintering (SPS) at temperatures from 750 řC to 850 řC. Dependence of microstructure and mechanical properties on the parameters of preparation was studied. During cryo-milling, powder particles significantly changed shape from ball-shaped to disc-shaped. Particles were not refined by milling, but severely plastically deformed. SEM observations showed that all prepared samples contain duplex alpha + beta structure. Volume fraction of alpha phase is significantly higher in the sintered milled powder due to increased beta- transus temperature caused by contamination by oxygen and also due to easier alpha phase precipitation caused by refined microstructure. Maximum microhardness of 350 HV was achieved for both types of sintered powders. High microhardness of sintered initial powder can be attributed to formation of omega phase during cooling, while sintered milled powder is strengthened by refined microstructure and small alpha phase precipitates. Cryogenic milling prior to...
The investigation of an Al-Zr-Ti alloy prepared by spark plasma sintering of atomized powder
Molnárová, O. ; Málek, P. ; Lukáč, František ; Chráska, Tomáš ; Cinert, Jakub
The microstructure and mechanical properties of a powder metallurgical Al-Zr-Ti alloy was studied. Fine powder with a typical size below 50 ?m was prepared by gas atomization. The smallest powder particles with a diameter below 10 ?m exhibited a segregation free microstructure. Larger droplets were found to contain intermetallic particles rich in Zr and Ti. The gas atomized powder was consolidated by spark plasma sintering (SPS) at various temperatures ranging from 450 to 550 °C. During SPS the materials microstructure remained nearly unchanged and a fine grain size between 2 and 3 ?m was observed. All SPS samples exhibited a microhardness of around 90 HV. The annealing (1 h, 500 °C) of the sample sintered at the highest temperature (550 °C) resulted in a decrease of microhardness to 75 HV as a result of changes in the phase composition, the fine grain size was retained. Natural aging at room temperature was not observed.
The effect of spark plasma sintering on the porosity and mechanical properties of Ti-15Mo alloy
Terynková, A. ; Kozlík, J. ; Bartha, K. ; Chráska, Tomáš ; Dlabáček, Zdeněk ; Stráský, J.
Metastable β-titanium alloys are receiving much interest for various applications such as aircraft industry and medicine thanks to their excellent mechanical properties and biocompatibility. The common way of preparing the titanium alloys is hindered by its production costs. Powder metallurgy (PM) approach is a promising route for cost-effective fabrication of titanium alloys due to possibility of near net shaping. In this study, binary biomedical Ti-15Mo alloy was prepared by PM. Gas atomized powder was sintered by spark plasma sintering (SPS) above the β-transus temperature of the studied alloy. The compaction of the powders was accomplished by short-time sintering. The effect of the time of sintering on the porosity and the microhardness in centre part as well as in periphery part of the sample was investigated. The samples revealed significant inhomogeneity the porosity increases with the distance from the centre of the specimen. With increasing sintering times the porosity decreases and simultaneously the microhardness increases.
Microstructure of commercially pure titanium after cryogenic milling and spark Plasma sintering
Kozlík, J. ; Harcuba, P. ; Stráský, J. ; Chráska, Tomáš ; Janeček, M.
Commercially pure titanium was prepared by advanced powder metallurgy methods with the aim to produce the ultra-fine grained material. Cryogenic attritor milling was used as a first step to refine the microstructure at liquid argon temperatures to suppress recovery and dynamic recrystallization. Spark plasma sintering was subsequently employed to produce bulk material, exploiting its ability to achieve fully dense structure in short time and thus to reduce the grain growth. In order to understand the undergoing microstructural changes during the process, detailed investigation was performed after each preparation step. Powder morphology was changed significantly after milling, while particle fragmentation was only limited. Grain size after sintering was in micrometer scale, relatively independent of sintering conditions.
Microstructure and Texture of Titanium Prepared by Powder Metallurgy
Kozlík, Jiří ; Stráský, Josef (advisor) ; Chráska, Tomáš (referee)
Bulk commercially pure titanium was prepared by powder metallurgy, namely by cryogenic milling and spark plasma sintering, with aim to produce ultra-fine grained material with enhanced strength. The microstructure of milled powders was investigated in detail by a novel method called transmission EBSD, which allowed the first direct observation of texture within the powder particles. This texture is similar to rolling texture, because of the similar nature of the defor- mation during milling. Microstructure observations revealed grains with the size under 100 nm. The influence of sintering parameters on material properties were studied by scan- ning electron microscopy including EBSD, X-ray diffraction and by microhardness measurements. The trade-off relationship between porosity and grain size was identified, fully dense material with ultra-fine grained microstructure could not be produced. Increased oxygen content was identified as a main strengthening factor, while porosity has significant deteriorating effect on mechanical properties. The texture of powder was retained in the bulk material. The possibility of stabilizing the microstructure by mechanical alloying of Ti with yttrium oxide nanoparticles was investigated with mixed results. The stabiliza- tion was successful, but several issues...
SPARK PLASMA SINTERING OF BALL MILLED AND ATOMIZED POWDER BASED ON Fe-Al
Šíma, V. ; Minárik, P. ; Chráska, Tomáš
High-quality compacts were prepared using the spark plasma sintering (SPS) method from powders of similar composition Fe-Al-Zr-B. The properties of the sintered compacts are strongly dependent on the morphology and properties of the feedstock powder. The first powder was obtained by ball milling of the as cast alloy and the second was prepared by atomization under argon atmosphere. The morphology and structure of the two powders are compared and mechanical properties and microstructure of compacts prepared under the same conditions of the SPS procedure are discussed. The milled powder has an irregular morphology and shape of the polycrystalline particles, which have a completely disordered BCC structure with considerable internal stresses, high concentration of structural defects and the presence of aluminum oxide. The atomized powder particles are nearly spherical, polycrystalline with ordered B2 structure, with no significant signs of internal stresses and oxidation. Microhardness of particles of both powders was measured and compared with the microhardness of compact materials, the results of compression tests of compacts at room temperature were compared and discussed.
THE INVESTIGATION OF AN Al7075 ALLOY PREPARED BY SPARK PLASMA SINTERING OF MILLED POWDERS
Molnárová, O. ; Málek, P. ; Nemeth, G. ; Kozlík, J. ; Lukáč, František ; Chráska, Tomáš ; Cinert, Jakub
Atomized powder of an Al7075 alloy was high energy ball milled at room and cryogenic temperatures and compacted by spark plasma sintering (SPS) method. The influence of processing parameters on phase composition and microstructure was studied by X-ray diffraction, light and scanning electron microscopy. The mechanical properties were characterized by microhardness measurements. The atomized powder contained a large volume fraction of intermetallic phases located predominantly in continuous layers separating cells or dendrites in the interior of individual powder particles. Consolidation by SPS destroyed partially this morphology and replaced it by individual particles located at boundaries of original powder particles, at cell boundaries or arranged in chains in previous dendritic regions. High energy milling destroyed most intermetallic particles and enriched the matrix by solute atoms. The high deformation energy introduced into the powder during milling enhanced microhardness up to 220 HV. Consolidation of milled powders by SPS led to the formation of very fine-grained structure with the grain size even below 1 μm and with the fraction of high-angle boundaries about 0.9. Two main types of heterogeneously distributed precipitates were found. The irregularly shaped precipitates with a size about 1 μm seemed to encompass areas with rod like nano-precipitates in most samples. A drop in microhardness to 118HV was observed after SPS, predominantly due to a release of introduced deformation energy.
Influence of isothermal exposure on microstructural changes resulting in delamination of eutectic Al2O3+ZrO2+SiO2 thermal barrier coatings
Jech, D. ; Čelko, L. ; Chráska, Tomáš ; Slámečka, K. ; Klakurková, L. ; Dubský, Jiří ; Švejcar, J.
Eutectic ceramic Al2O3-ZrO2-SiO2 also termed Eucor (as a top coat) and CoNiCrAlY (as a bond coat) coatings were sprayed onto the surface of recently developed fine-grained cast polycrystalline nickel-based superalloy Inconel 713 LC by means of water stabilized plasma (WSP) and atmospheric plasma spraying (APS) techniques, respectively.Specimens were subjected to isothermal oxidation at 1050 °C for 10, 50, 100, 200 and 500 hours in ambient atmosphere,prior to which a half of the as-sprayed specimens was annealed at the temperature of 950 °C for 10 hours.Influence of short-time and long-time isothermal exposure on interactions at the bond-coat/top-coat interface was studied.The uniform and continuous oxide layer,also termed the thermally grown oxide (TGO),was formed and grew at the bond-coat/top-coat interface in all samples, both with and without the heat pre-treatment. Relationship between the dwell time, heat treatment and TGO growth kinetics was quantified.Microstructural changes
Chemical aspects of antiballistic cermets preparation
Brožek, Vlastimil ; Kubatík, Tomáš František ; Chráska, Tomáš ; Mušálek, Radek ; Janata, Marek ; Mastný, L.
The paper aims to demonstrate the possibilities of metal-ceramic material deposition on different types of metal or ceramic substrates using plasma deposition. A number of self-supporting components and the preparation of metal-braced composites are described and the results of plasma depositions of two particular extremely hard ceramic materials, boride and nitride of titanium are presented. The plasma deposition of these material is performed in technological conditions which prevent undesirable high-temperature oxidation. The paper describes deposition conditions that may lead to materials suited to create anti-ballistic protection and complicated shapes or improve parameters of surface layers of present anti-ballistic ceramics.
Properties of Novel Hybrid Water-Gas DC Arc Plasma Torch
Chráska, Tomáš ; Hrabovský, Milan ; Glanc, Aleš ; Mušálek, Radek ; Medřický, Jan
A new type of plasma torch with combined stabilization of electric arc by water vortex and gas flow is presented. This hybrid water/gas stabilization offers the possibility of adjusting plasma jet parameters within a wide range from high-enthalpy low-density plasmas typical for liquid stabilized torches to lower enthalpy higher density plasmas generated in gas stabilized torches. Moreover, gas flow in the cathode part protects a cathode tip and thus a consumable graphite cathode used in water-only stabilized plasma torches could be replaced by a fixed tungsten cathode. Examples of hybrid WSP torch utilization for high temperature application are given.

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