Národní úložiště šedé literatury Nalezeno 89 záznamů.  1 - 10dalšíkonec  přejít na záznam: Hledání trvalo 0.00 vteřin. 
Hollow-fibre Based Microextraction and Voltammetric Determination of Vanillylmandelic Acid
Hrdlička, Vojtěch ; Barek, J. ; Navrátil, Tomáš
New method of liquid/liquid/liquid hollow fibre based microextraction of vanillylmandelic acid coupled with voltammetric determination is being developed. Selected liquid membranes based on alcohols, aliphatic hydrocarbons and esters were tested. Highest enrichment factor of 2.52 after 30 minutes of extraction was obtained using propyl benzoate, RSD = 18.2 % (n=5). Mechanically and cathodically pretreated (-1000 mV vs. Ag/AgCl/3M KCl, 15 s) boron doped diamond electrode in a miniaturized arrangement was used for DPV determination. LOD = 1.2 micromol/l, RSD = 5.9% (n=10) for a 10 microl extract.
Silver Solid Amalgam Electrodes as Perspective Tools for Sensitive Voltammetric Determinations of Food Azo Dyes Amaranth and Allura Red AC
Tvorynska, S. ; Barek, J. ; Josypčuk, Bohdan
In this paper, for the first time, the electrochemical behaviours of the food azo dyes Amaranth (E 123) and Allura Red AC (E 129) were investigated on two modifications of silver solid amalgam electrode, namely mercury meniscus modified, polished and compared with hanging mercury drop electrode using differential pulse voltammetry and direct current voltammetry. The effect of adsorption and the reduction mechanism on tested electrodes were described in detail. Measurements with amalgam electrodes showed good reproducibility, stability and high sensitivity. As a result, they were successfully applied for the determination of investigated azo dyes in different commercial drink samples.
HPLC-ED/UV with Solid Phase Extraction for the Determination of 5-Hydroxyindole-3-acetic Acid
Makrlíková, Anna ; Dejmková, H. ; Navrátil, Tomáš ; Barek, J. ; Vyskočil, V.
Determination of 5-HIAA in human urine was successfully performed using HPLC-ED/UV with SPE. HPLC-ED is a very sensitive technique, presented method does not need any sample pre-treatment apart from SPE procedure, which replaced filtration of samples of human urine to avoid problems with clogging a HPLC column. The found native\nconcentrations of 5-HIAA in human urine using HPLC-ED with SPE fully corresponds with published normal concentrations in urine (17.8 - 58.3 micromol l-1). The found native concentrations of 5-HIAA were 18.4 micromol L-1 (calculated from peak height). The presented method is fast and could be used for simple\nscreening of human urine, because HPLC-ED/UV allows simultaneous determination of 5-HIAA, HVA, and VMA as important tumour biomarkers.
Aplikace mikro-objemové voltametrické cely pro stanovení doxorubicinu hydrochloridu
Skalová, Štěpánka ; Navrátil, Tomáš ; Barek, J. ; Vyskočil, V.
Byla úspěšně otestována aplikace mikro-objemové voltametrické cely na příkladu stanovení protinádorového léčiva doxorubicinu hydrochloridu. Objem analyzovaného vzorku činil 50 mikroL s LOD 0,39 micromol L-1 a LDR 0,4-10 mikromol L-1. Tato mikro-objemová cela byla také úspěšně použita k analýze tohoto analytu v modelových vzorcích pitné vody a lidské moči.
Supported Liquid Membranes for Hollow-Fibre Based Microextraction and Voltammetric Determination of Neuroblastoma Biomarkers
Josypčuk, Bohdan ; Barek, J. ; Josypčuk, Oksana
A new type of tubular detector (TD+AuxE) was proposed, fabricated, tested and compared\nwith a typical silver amalgam tubular detector developed earlier. Non-stop-flow differential\npulse voltammetric anodic stripping method (AS-DPV) and amperometric method in a\nglucose oxidase biosensor arrangement were tested. Both detectors were applied for AS-DPV\nmeasurements in flow systems for the first time. The proposed combination of tubular\ndetector with auxiliary electrode provides a much greater current response than the classic\narrangement with three individual electrodes. All relevant parameters (potentials of\naccumulation or detection, flow rate, analyte concentrations, shielding sleeve length, etc.)\nwere optimized for the developed TD+AuxE.
Supported Liquid Membranes for Hollow-Fibre Based Microextraction and Voltammetric Determination of Neuroblastoma Biomarkers
Hrdlička, Vojtěch ; Barek, J. ; Navrátil, Tomáš
Novel method of three phase hollow fibre based liquid/liquid/liquid microextraction coupled\nwith voltammetric determination of clinical biomarkers homovanillic and vanillylmandelic\nacid is being developed. Wide variety of water-immiscible supported liquid membranes\n(SLMs) were tested. Highest enrichment factors were obtained using butyl benzoate as SLM.\nEnrichment factors for 30 min HF-LPME were 3. 0.74 for HVA and 5. 0.45 for VMA,\nrespectively. Repeatability of HF-LPME of microM HVA or VMA was 19.0% for HVA and\n7.9 % for VMA (n=5), respectively.

Národní úložiště šedé literatury : Nalezeno 89 záznamů.   1 - 10dalšíkonec  přejít na záznam:
Viz též: podobná jména autorů
6 Barek, J.
2 Barek, Jan
2 Barek, Jaroslav
1 Barek, Jiří
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