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Study of structural and mechanical properties of dendrimers
Ščudlová, Jolana ; Legut,, Dominik (referee) ; Žídek, Jan (advisor)
This thesis deals with the research on organized supermolecular structures. These structures are present in many polymeric materials. Mainly in bio-materials, they cause biological activity. Collagen fibril and dendrimers are suitable materials for molecular modeling. Collagen is natural protein with long, fibrous structure. Its fibrils show high elasticity. This property makes the material useful for certain applications. Dendrimers are synthetic macromolecules with regular and highly branched architecture. Modeling of their properties can be useful for improvement of various molecular models. The molecular structure of collagen fibril and dendrimers was studied by molecular dynamics simulations. The structures were built in the GROMACS software. Elastic deformation of collagen fibril was investigated. In case of dendrimers, shape and gyration radii were calculated from molecular models. Properties of these two materials are well described in literature. Therefore, modeling results can be compared to experimentally measured properties.
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Analysis of mechanical properties of polymers and polymer compsites from video record of tensile test
Ščudlová, Jolana ; Nezbedová, Eva (referee) ; Žídek, Jan (advisor)
This thesis described mechanical tests with monitoring of camera. The aim of this work is to obtain additional information about material behavior during the test. The mechanical tests were monitored high-definition (HD) digital video-camera and camera with high resolution. The method was applied to the tensile test and Pennsylvania notch test (PENT test). The videorecordings were processed with the assistance image analysis method. The marks were placed on both of these specimens, mutual movement these marks were used to obtain following characteristics. It was Poisson’s ratio and true stress by tensile test. By PENT test it was rate growth crack. The investigated material was elastomeric polyurethane filled by biodegradable polyhydroxybutyrate for tensile test. Second material was polypropylene for PENT test. The camera is adding to the test gives extended information about the material and better interpretation results.
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Analysis of mechanical properties of polymers and polymer compsites from video record of tensile test
Ščudlová, Jolana ; Nezbedová, Eva (referee) ; Žídek, Jan (advisor)
This thesis described mechanical tests with monitoring of camera. The aim of this work is to obtain additional information about material behavior during the test. The mechanical tests were monitored high-definition (HD) digital video-camera and camera with high resolution. The method was applied to the tensile test and Pennsylvania notch test (PENT test). The videorecordings were processed with the assistance image analysis method. The marks were placed on both of these specimens, mutual movement these marks were used to obtain following characteristics. It was Poisson’s ratio and true stress by tensile test. By PENT test it was rate growth crack. The investigated material was elastomeric polyurethane filled by biodegradable polyhydroxybutyrate for tensile test. Second material was polypropylene for PENT test. The camera is adding to the test gives extended information about the material and better interpretation results.
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Study of structural and mechanical properties of dendrimers
Ščudlová, Jolana ; Legut,, Dominik (referee) ; Žídek, Jan (advisor)
This thesis deals with the research on organized supermolecular structures. These structures are present in many polymeric materials. Mainly in bio-materials, they cause biological activity. Collagen fibril and dendrimers are suitable materials for molecular modeling. Collagen is natural protein with long, fibrous structure. Its fibrils show high elasticity. This property makes the material useful for certain applications. Dendrimers are synthetic macromolecules with regular and highly branched architecture. Modeling of their properties can be useful for improvement of various molecular models. The molecular structure of collagen fibril and dendrimers was studied by molecular dynamics simulations. The structures were built in the GROMACS software. Elastic deformation of collagen fibril was investigated. In case of dendrimers, shape and gyration radii were calculated from molecular models. Properties of these two materials are well described in literature. Therefore, modeling results can be compared to experimentally measured properties.
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