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Original title:
A New Look on the Nernst Model in Electrochemistry
Authors: Wein, Ondřej
Document type: Papers
Conference/Event: Konference chemického a procesního inženýrství CHISA 2011 /58./, Srní, Šumava (CZ), 2011-10-24 / 2011-10-27
Year: 2011
Language: eng
Abstract: The present paper is inspired by the electrodiffusion (ED) flow measurement, utilizing the limiting-diffusion regime (LDR) in two-electrode ED cells. The electrochemical testing and calibrations of the ED cells is based on two standard electrochemical techniques - quasi-steady voltammetry and voltage-step transient. Recently published theory of the voltage-step transient under simultaneous effect of Faradaic and Ohmic resistances is based on a suitably extended Nernst model. An analogous theory of the voltammetric experiment is presented here.
Keywords: nernst model of diffusion layer; primary current distribution; voltammetric curve
Project no.: CEZ:AV0Z40720504 (CEP)
Host item entry: Sborník, ISBN 978-80-905035-0-2
Note: Související webová stránka: www.chisa.cz/2011
Institution: Institute of Chemical Process Fundamentals AS ČR (web)
Original record: http://hdl.handle.net/11104/0201948
Permalink: http://www.nusl.cz/ntk/nusl-71612
The record appears in these collections:
Research > Institutes ASCR > Institute of Chemical Process Fundamentals
Conference materials > Papers
Authors: Wein, Ondřej
Document type: Papers
Conference/Event: Konference chemického a procesního inženýrství CHISA 2011 /58./, Srní, Šumava (CZ), 2011-10-24 / 2011-10-27
Year: 2011
Language: eng
Abstract: The present paper is inspired by the electrodiffusion (ED) flow measurement, utilizing the limiting-diffusion regime (LDR) in two-electrode ED cells. The electrochemical testing and calibrations of the ED cells is based on two standard electrochemical techniques - quasi-steady voltammetry and voltage-step transient. Recently published theory of the voltage-step transient under simultaneous effect of Faradaic and Ohmic resistances is based on a suitably extended Nernst model. An analogous theory of the voltammetric experiment is presented here.
Keywords: nernst model of diffusion layer; primary current distribution; voltammetric curve
Project no.: CEZ:AV0Z40720504 (CEP)
Host item entry: Sborník, ISBN 978-80-905035-0-2
Note: Související webová stránka: www.chisa.cz/2011
Institution: Institute of Chemical Process Fundamentals AS ČR (web)
Original record: http://hdl.handle.net/11104/0201948
Permalink: http://www.nusl.cz/ntk/nusl-71612
The record appears in these collections:
Research > Institutes ASCR > Institute of Chemical Process Fundamentals
Conference materials > Papers
Record created 2011-11-25, last modified 2024-01-26
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