Název: Geopolymers Incorporating Wastes and Composites Processing
Překlad názvu: Geopolymers Incorporating Wastes and Composites Processing
Autoři: Taveri, Gianmarco ; Perná,, Ivana (oponent) ; Pouchlý, Václav (oponent) ; Dlouhý, Ivo (vedoucí práce)
Typ dokumentu: Disertační práce
Rok: 2019
Jazyk: eng
Nakladatel: Vysoké učení technické v Brně. Fakulta strojního inženýrství
Abstrakt: Buildings construction and realization of public infrastructures have always been a primary need in the human society, developing low cost and user-friendly materials which also encounter safety and durability requirements. Portland cement is the most used material in construction industry from the industrial revolution up to date, but the raising concerns related to the climate change are pushing the governments worldwide to replace it with more eco-friendly and greener materials. Geopolymers are considered to be best alternatives to Portland cement in construction industry, but issues related to cost and mechanical properties are still hindering the commercialization of this material. Geopolymer incorporating wastes is one of the solutions. Fly ash, a thermal power plant by-product, and borosilicate glass, a recycled glass from pharmaceutical vials, are suitable candidates in geopolymers activation. NMR and FTIR spectroscopies demonstrated that borates from borosilicate glass are active compounds in geopolymerization, substituting the alumina is its role, composing a B-Al-Si network never observed before. Various fly ash and borosilicate glass weight contents were studied in terms of mechanical properties (compression test, 3-point bending test). It was found that fly ash 55 wt.% and borosilicate 45 wt.% composition activated in 13 M NaOH solution holds the best compressive and flexural strength (45 and 4 MPa respectively), 25% stronger than similar counterparts found in literature. Cellulose fibres in different weight contents were dispersed into the geopolymeric paste to produce geopolymer composites, with the aim to render the material more suitable for structural applications. 3-point bending test showed an improvement of the flexural strength of about 165% (12 MPa), while the chevron notch method displayed a fracture toughness of 0.7 MPam1/2, in line with the results of geopolymer composites found in literature. In this thesis work, fly ash was also successfully densified in 3 M NaOH solution and distilled water through a new method based on hydraulic pressure, called hydro-pressure sintering. This innovative technology involves a drastic reduction of NaOH utilization in geopolymerization, rendering the material more eco-friendly. XRD spectroscopy conducted on produced samples revealed a higher formation of crystals, most likely induced by the application of hydraulic pressure (450 MPa).
Klíčová slova: composite materials; fracture toughness; Geopolymers; hydro-pressure sintering; mechanical properties; polycondensation; spectroscopy.; composite materials; fracture toughness; Geopolymers; hydro-pressure sintering; mechanical properties; polycondensation; spectroscopy.

Instituce: Vysoké učení technické v Brně (web)
Informace o dostupnosti dokumentu: Plný text je dostupný v Digitální knihovně VUT.
Původní záznam: http://hdl.handle.net/11012/180701

Trvalý odkaz NUŠL: http://www.nusl.cz/ntk/nusl-403861


Záznam je zařazen do těchto sbírek:
Školství > Veřejné vysoké školy > Vysoké učení technické v Brně
Vysokoškolské kvalifikační práce > Disertační práce
 Záznam vytvořen dne 2019-10-19, naposledy upraven 2022-09-04.


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