Original title: Potential-driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-derived Polymers.
Authors: Žádný, Jaroslav ; Storch, Jan ; Strašák, Tomáš ; Církva, Vladimír ; Hrbáč, J. ; Fekete, Ladislav ; Pokorný, Jan ; Bulíř, Jiří ; Vacek, J.
Document type: Papers
Conference/Event: Advances in Organic, Bioorganic and Pharmaceutical Chemistry Liblice 2017 /52./, Lázně Bělohrad (CZ), 20171103
Year: 2017
Language: eng
Abstract: 3-([7]H elicen-9-yl)-thiophene hybrid monomer was electrooxidized in acetonitrile by cyclic voltammetry with anodic potential limits of +1.5 V or +2.5 V, resulting in a conductive and non-conductive polymer, respectively. The electrochemical findings were supplemented by microscopy investigations; UV-Vis, fluorescence and vibrational spectroscopies, ellipsometry measurements and computational chemistry. The electrodeposited polymers could be used for the further development of materials applicable in organic electronics and sensing technologies.
Keywords: anodic reaction; electrosynthesis; helicene
Project no.: GA17-02578S (CEP)
Funding provider: GA ČR
Host item entry: Book of Abstracts, ISBN N.
Rights: This work is protected under the Copyright Act No. 121/2000 Coll.

Institution: Institute of Chemical Process Fundamentals AS ČR (web)
Original record: http://hdl.handle.net/11104/0277637

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