Original title: Determination of the Rate of Tetraethylammonium Ion Transfer across the\nWater/1,2-DCE Interface with Steady-State Voltammetry at a Nano-ITIES
Authors: Silver, Barry Richard ; Holub, Karel ; Mareček, Vladimír
Document type: Papers
Conference/Event: Moderní elektrochemické metody /37./, Jetřichovice (CZ), 20170515
Year: 2017
Language: eng
Abstract: The rate of TEA+ ion transfer across the water/1,2-dichloroethane interface has been\nmeasured using steady-state cyclic voltammetry at a capillary with an orifice of nano-sized\ndimension. It was found that the average rate constant for TEA+ transfer from water to oil and\nfrom oil to water is 0.64 cm/s. The results are repeatable using the same capillary. This value\nis similar to that measured previously using electrochemical impedance spectroscopy and\nfluctuation analysis at the micro-interface.
Keywords: Ion transfer kinetics; Nanocapillary; Tetraethylammonium ion
Project no.: GA17-09980S (CEP)
Funding provider: GA ČR
Host item entry: XXXVII. Moderní elektrochemické metody. Sborník přednášek mezinárodní odborné konference, ISBN 978-80-905221-5-2

Institution: J. Heyrovsky Institute of Physical Chemistry AS ČR (web)
Document availability information: Fulltext is available on demand via the digital repository of the Academy of Sciences.
Original record: http://hdl.handle.net/11104/0271994

Permalink: http://www.nusl.cz/ntk/nusl-317295


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Research > Institutes ASCR > J. Heyrovsky Institute of Physical Chemistry
Conference materials > Papers
 Record created 2017-06-12, last modified 2023-12-06


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