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Original title:
Process-Based Model of Mixed-Matrix Membrane
Authors: Čapek, P. ; Hejtmánek, Vladimír ; Veselý, M. ; Sysel, P. ; Kočiřík, Milan ; Brabec, Libor ; Zikánová, Arlette ; Bernauer, B. ; Fíla, V.
Document type: Papers
Conference/Event: International Congress of Chemical and Process Engineering CHISA 2012 and 15th Conference PRES 2012 /20./, Prague (CZ), 2012-08-25 / 2012-08-29
Year: 2012
Language: eng
Abstract: The focus of this contribution was on the formulation and verification of a process-based model of the mixed-matrix membrane that consisted of the polyimide matrix synthesized from the monomers 4,4’-(hexafluoroisopropylidene)diphtalic anhydride and 4,4’-oxydianiline, and silicalite-1. When a solution of a polyimide precursor in N,N-dimethylformamide was ready, silicalite-1 particles were dispersed in the solution and the dispersion was subsequently cast on a Teflon support plate. An initial mass ratio of silicalite-1 and polyimide was about 1:1. After solvent removal, the films were heated in subsequent steps up to 230°C for two hour. From a process-based model point of view, a key operation of the entire synthesis was slow sedimentation of silicalite particles in the viscous solution. Preliminary observation of 2D cuts through the solid membrane in a scanning electron microscope revealed that there were a lot of contacts among the silicalite particles. Therefore, a sequential (ballistic) deposition algorithm, well representing sedimentation in a low-energy environment, was used to create an off-lattice model of spatial distribution of the silicalite particles in the polyimide matrix.
Keywords: composite material; gas separation processes; mixed-matrix membrane
Host item entry: Final Program, ISBN 978-80-905035-1-9
Note: Související webová stránka: www.chisa.cz/2012
Rights: This work is protected under the Copyright Act No. 121/2000 Coll.
Institution: Institute of Chemical Process Fundamentals AS ČR (web)
Original record: http://hdl.handle.net/11104/0212157
Permalink: http://www.nusl.cz/ntk/nusl-126625
The record appears in these collections:
Research > Institutes ASCR > Institute of Chemical Process Fundamentals
Conference materials > Papers
Authors: Čapek, P. ; Hejtmánek, Vladimír ; Veselý, M. ; Sysel, P. ; Kočiřík, Milan ; Brabec, Libor ; Zikánová, Arlette ; Bernauer, B. ; Fíla, V.
Document type: Papers
Conference/Event: International Congress of Chemical and Process Engineering CHISA 2012 and 15th Conference PRES 2012 /20./, Prague (CZ), 2012-08-25 / 2012-08-29
Year: 2012
Language: eng
Abstract: The focus of this contribution was on the formulation and verification of a process-based model of the mixed-matrix membrane that consisted of the polyimide matrix synthesized from the monomers 4,4’-(hexafluoroisopropylidene)diphtalic anhydride and 4,4’-oxydianiline, and silicalite-1. When a solution of a polyimide precursor in N,N-dimethylformamide was ready, silicalite-1 particles were dispersed in the solution and the dispersion was subsequently cast on a Teflon support plate. An initial mass ratio of silicalite-1 and polyimide was about 1:1. After solvent removal, the films were heated in subsequent steps up to 230°C for two hour. From a process-based model point of view, a key operation of the entire synthesis was slow sedimentation of silicalite particles in the viscous solution. Preliminary observation of 2D cuts through the solid membrane in a scanning electron microscope revealed that there were a lot of contacts among the silicalite particles. Therefore, a sequential (ballistic) deposition algorithm, well representing sedimentation in a low-energy environment, was used to create an off-lattice model of spatial distribution of the silicalite particles in the polyimide matrix.
Keywords: composite material; gas separation processes; mixed-matrix membrane
Host item entry: Final Program, ISBN 978-80-905035-1-9
Note: Související webová stránka: www.chisa.cz/2012
Rights: This work is protected under the Copyright Act No. 121/2000 Coll.
Institution: Institute of Chemical Process Fundamentals AS ČR (web)
Original record: http://hdl.handle.net/11104/0212157
Permalink: http://www.nusl.cz/ntk/nusl-126625
The record appears in these collections:
Research > Institutes ASCR > Institute of Chemical Process Fundamentals
Conference materials > Papers
Record created 2012-10-26, last modified 2023-12-11
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